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Nanoscale Double Interfacial Layers for Improved Photovoltaic Effect of Polymer Solar Cells

이중 나노 계면층을 적용한 고효율 고분자 태양 전지 소자 연구

  • 이영인 (광운대학교 전자물리학과) ;
  • 박병주 (광운대학교 전자물리학과)
  • Received : 2010.06.01
  • Accepted : 20100000
  • Published : 2011.01.01

Abstract

We introduced nanoscale interfacial layers between the PV layer and the cathode in poly (3-hexylthiophene):methanofullerene bulk-heterojunction polymer photovoltaic (PV) cells. The nanoscale double interfacial layers were made of ultrathin poly (oxyethylenetridecylether) surfactant and low-work-function alloy-metal of Al:Li layers. It was found that the nanoscale interfacial layers increase the photovoltaic performance, i.e., increasing short-circuit current density and fill factor with improved device stability. For PV cells with the nanoscale double interfacial layers, an increase in power conversion efficiency of $4.18{\pm}0.24%$ was achieved, compared to that of the control devices ($3.89{\pm}0.08%$) without the double interfacial layers.

Keywords

References

  1. N. S. Sariciftci, L. Smilowitz, A. J. Heeger, and F. Wudl, Science, 258, 1474 (1992). https://doi.org/10.1126/science.258.5087.1474
  2. G. Yu, J. Gao, J. C. Hummelen, F. Wudl, and A. J. Heeger, Science, 270, 1789 (1995). https://doi.org/10.1126/science.270.5243.1789
  3. C. J. Brabec, N. S. Sariciftci, and J. C. Hummelen, Adv. Funct. Mater., 11, 15 (2001). https://doi.org/10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO;2-A
  4. G. Li, V. Shrotriya, Y. Yao, and Y. Yang, J. Appl. Phys., 98, 043704 (2005). https://doi.org/10.1063/1.2008386
  5. W. Ma, C. Yang, X. Gong, K. Lee, and A. J. Heeger, Adv. Funct. Mater., 15, 1617 (2005). https://doi.org/10.1002/adfm.200500211
  6. H.-Y. Chen, J. Hou, S. Zhang, Y. Liang, G. Yang, Y. Yang, L. Yu, Y. Wu, and G. Li, Nat. Photon., 3, 649 (2009). https://doi.org/10.1038/nphoton.2009.192
  7. F. C. Krebs, Sol. Energy Mater. Sol. Cells, 93, 394 (2009). https://doi.org/10.1016/j.solmat.2008.10.004
  8. F. C. Krebs, S. A. Gevorgyan, and J. Alstrup, J. Mater. Chem., 19, 5442 (2009). https://doi.org/10.1039/b823001c
  9. F. L. Zhang, M. Johansson, M. R. Andersson, J. C. Hummelen, and O. Inganas, Adv. Mater., 14, 662 (2002). https://doi.org/10.1002/1521-4095(20020503)14:9<662::AID-ADMA662>3.0.CO;2-N
  10. S. Khodabakhsh, B. M. Sanderson, J. Nelson, and T. S. Jones, Adv. Funct. Mater., 16, 95 (2006). https://doi.org/10.1002/adfm.200500207
  11. C. J. Brabec, S. E. Shaheen, C. Winder, N. S. Sariciftci, and P. Denk, Appl. Phys. Lett., 80, 1288 (2002). https://doi.org/10.1063/1.1446988
  12. F. Zhang, M. Ceder, and O. Inganas, Adv. Mater., 19, 1835 (2007). https://doi.org/10.1002/adma.200602597
  13. K. Lee, J. Y. Kim, S. H. Park, S. H. Kim, S. Cho, and A. J. Heeger, Adv. Mater., 19, 2445 (2007). https://doi.org/10.1002/adma.200602653
  14. H.-L. Yip, S. K. Hau, N. S. Baek, H. Ma, and A. K.-Y. Jen, Adv. Mater., 20, 2376 (2008). https://doi.org/10.1002/adma.200703050
  15. J. H. Park, S. S. Oh, S. W. Kim, E. H. Choi, B. H. Hong, Y. H. Seo, G. S. Cho, B. Park, J. Lim, S. C. Yoon, and C. Lee, Appl. Phys. Lett., 90, 153508 (2007). https://doi.org/10.1063/1.2721872
  16. Y. Ding, P. Lu, and Q. Chen, Proc. SPIE 7099, 709919 (2008). https://doi.org/10.1117/12.806958
  17. Y. I. Lee, M. Kim, Y. H. Huh, J. S. Lim, S. C. Yoon, and B. Park, Sol. Energy Mater. Sol. Cells, 94, 1152 (2010). https://doi.org/10.1016/j.solmat.2010.02.045
  18. C. Waldauf, M. C. Scharber, P. Schilinsky, J. A. Hauch, and C. J. Brabec, J. Appl. Phys., 99, 104503 (2006). https://doi.org/10.1063/1.2198930
  19. Y.-H. Niu, H. Ma, Q. Xu, and A. K.-Y. Jen, Appl. Phys. Lett., 86, 083504 (2005). https://doi.org/10.1063/1.1865327
  20. C. Fery, B. Racine, D. Vaufrey, H. Doyeux, and S. Cina, Appl. Phys. Lett., 87, 213502 (2005). https://doi.org/10.1063/1.2133922
  21. K. Norrman, S. A. Gevorgyan, and F. C. Krebs, ACS Appl. Mater. Interfaces, 1, 102 (2009). https://doi.org/10.1021/am800039w
  22. M. Jorgensen, K. Norrman, and F. C. Krebs, Sol. Energy Mater. Sol. Cells, 92, 686 (2008). https://doi.org/10.1016/j.solmat.2008.01.005