Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Zinc Porphyrin-Cored Dendrimers; Axial Coordination of Pyridine and Photoinduced Electron Transfer to Methyl Viologen

  • Park, Ji-Eun (Department of Chemistry, Sunchon National University) ;
  • Choi, Dae-Ock (Department of Chemistry, Sunchon National University) ;
  • Shin, Eun-Ju (Department of Chemistry, Sunchon National University)
  • Received : 2011.09.02
  • Accepted : 2011.10.06
  • Published : 2011.12.20
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Abstract

The porphyrin-incorporated arylether dendrimers ZnP-D1 and ZnP-D4 were investigated to discover the influence of dendritic environments for the axial ligation of pyridine and photoinduced electron transfer by methyl viologen. Absorption and fluorescence spectra of ZnP, ZnP-D1, and ZnP-D4 were measured in dichloromethane with the addition of pyridine or methyl viologen dichloride. Axial ligation of pyridine was confirmed by red-shifted absorption spectrum. The complex formation constants $K_f$ (Table 1) for axial coordination of pyridine on ZnP, ZnP-D1, and ZnP-D4 were estimated to be $4.4{\times}10^3\;M^{-1}$, $3.3{\times}10^3\;M^{-1}$, and $1.7{\times}10^3\;M^{-1}$, respectively. The photoinduced electron transfer to methyl viologen dichloride was confirmed by fluorescence quenching. Stern-Volmer constants Ksv for ZnP, ZnP-D1, and ZnP-D4 were calculated to be $2.6{\times}10^3$, $2.5{\times}10^3$, and $2.1{\times}10^3$, respectively. ZnP-D4 surrounded by 4 aryl ether dendrons shows the smallest $K_f$ and Ksv values, with comparison to ZnP and ZnP-D1.

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