Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Structure Optimization of Di-ionizable Calixarene Nano-baskets for Competitive Solvent Extraction of Alkali and Alkaline Earth Metals

  • Mokhtari, Bahram (Department of Chemical Engineering, Shahreza Branch, Islamic Azad University) ;
  • Pourabdollah, Kobra (Department of Chemical Engineering, Shahreza Branch, Islamic Azad University)
  • Received : 2011.07.25
  • Accepted : 2011.08.31
  • Published : 2011.11.20
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Abstract

The competitive solvent extractions of alkali and alkaline earth metals by di-ionizable calix[4]arene nano-baskets were studied using nine conformers of calix[4]arene nano-baskets. The objective of this work is to assess the variation of macrocycle conformation, orientation and position of pendant moieties upon the extraction parameters (efficiency, selectivity and $pH_{1/2}$) of the complexes. The results revealed that alternation of ring conformation in calixarene scaffold affects the solvent extraction parameters towards alkali and alkaline earth metals, while changing the orientation of pendant moieties from ortho- to para- as well as cis- to trans-analogues depicted no changes in those extraction parameters.

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References

  1. Mokhtari, B.; Pourabdollah, K.; Dalali, N. J. Incl. Phenom. Macrocycl. Chem. 2011, 69, 1. https://doi.org/10.1007/s10847-010-9848-7
  2. Mokhtari, B.; Pourabdollah, K.; Dalali, N. J. Coord. Chem. 2011, 64, 743. https://doi.org/10.1080/00958972.2011.555538
  3. Mokhtari, B.; Pourabdollah, K.; Dallali, N. J. Radioanal. Nucl.Chem. 2011, 287, 921. https://doi.org/10.1007/s10967-010-0881-1
  4. Mokhtari, B.; Pourabdollah, K.; Dalali, N. Chromatographia 2011, 73, 829. https://doi.org/10.1007/s10337-011-1954-1
  5. Mokhtari, B.; Pourabdollah, K. Asian J. Chem. 2011, 23, 4717.
  6. Baeyer, A. Chem. Ber. 1872, 5, 280. https://doi.org/10.1002/cber.18720050186
  7. Zinke, A.; Ziegler, E. Chem. Ber. 1944, 77, 264. https://doi.org/10.1002/cber.19440770322
  8. Gutsche, C. D.; Muthukrishnan, R. J. Org. Chem. 1978, 43, 4905. https://doi.org/10.1021/jo00419a052
  9. Maharaj, F.; Craig, D. C.; Scudder, M. L.; Bishop, R.; Kumar, N. J. Incl. Phenom. Macrocycl. Chem. 2007, 59, 17. https://doi.org/10.1007/s10847-006-9288-6
  10. Yang, Y.; Cao, X.; Surowiec, K.; Bartsch, R. A. J. Incl. Phenom. Macrocycl. Chem. 2011, 69, 163.
  11. Atanassova, M.; Lachkova, V.; Vassilev, N.; Varbanov, S.; Dukov, I. J. Incl. Phenom. Macrocycl. Chem. 2007, 58, 173. https://doi.org/10.1007/s10847-006-9140-z
  12. Zhang, D.; Crawford, J. D.; Bartsch, R. A. J. Incl. Phenom. Macrocycl. Chem. 2010, 66, 163. https://doi.org/10.1007/s10847-009-9675-x
  13. Bennouna, L.; Vicens, J.; Asfari, Z.; Yahyaoui, A.; Burgard, M. J. Incl. Phenom. Macrocycl. Chem. 2001, 40, 95. https://doi.org/10.1023/A:1011110827429
  14. Rydberg, J.; Cox, M.; Musikas, C.; Choppin, G. R. Solvent Extraction Principles and Practice; Dekker, M., Ed.; CRC: New York, U.S.A., 2004; p 20.
  15. Ocak, Ü.; Ocak, M.; Surowiec, K.; Bartsch, R. A.; Gorbunova, M. G.; Tu, C.; Surowiec, M. J. Incl. Phenom. Macrocycl. Chem. 2009, 63, 131. https://doi.org/10.1007/s10847-008-9497-2
  16. Zhang, D.; Crawford, J. D.; Bartsch, R. A. Tetrahedron 2008, 64, 9843. https://doi.org/10.1016/j.tet.2008.07.115
  17. Tu, C.; Surowiec, K.; Gega, J.; Purkiss, D. W.; Bartsch, R. A. Tetrahedron 2008, 64, 1187. https://doi.org/10.1016/j.tet.2007.11.065
  18. Zhang, D.; Cao, X.; Purkiss D. W.; Bartsch, R. A. Org. Biomol. Chem. 2007, 5, 1251. https://doi.org/10.1039/b700072c
  19. Zhou, H.; Liu, D.; Gega, J.; Surowiec, K.; Purkiss, D. W.; Bartsch, R. A. Org. Biomol. Chem. 2007, 5, 324-332. https://doi.org/10.1039/b611570e
  20. Tu, C.; Surowiec, K.; Bartsch, R. A. Tetrahedron 2007, 63, 4184. https://doi.org/10.1016/j.tet.2007.02.105
  21. Mokhtari, B.; Pourabdollah, K. J. Coord. Chem. 2011, 64, 3081. https://doi.org/10.1080/00958972.2011.613462
  22. Mokhtari, B.; Pourabdollah, K. J. Coord. Chem. 2011, 64, 3189. https://doi.org/10.1080/00958972.2011.616930
  23. Mokhtari, B.; Pourabdollah, K. J. Incl. Phenom. Macrocycl. Chem. 2011. doi: 10.1007/s10847-011-0052-1.
  24. Mokhtari, B.; Pourabdollah, K. J. Incl. Phenom. Macrocycl. Chem. 2011. doi: 10.1007s10847-011-0062-z. https://doi.org/10.1007s10847-011-0062-z
  25. Mokhtari, B.; Pourabdollah, K. Supramol. Chem. 2011. doi: 10.1080/10610278.2011.605452.
  26. Mokhtari, B.; Pourabdollah, K. J. Therm. Anal. Calorim. 2011. doi: 10.1007/s10973-011-2014-7.

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