Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Polyol Synthesis of Ruthenium Selenide Catalysts for Oxygen Reduction Reaction

  • Lee, Ki-Rak (Department of Chemical and Biomolecular Engineering (BK21 Graduate Program), Korea Advanced Institute of Science and Technology) ;
  • Woo, Seong-Ihl (Department of Chemical and Biomolecular Engineering (BK21 Graduate Program), Korea Advanced Institute of Science and Technology)
  • Received : 2010.07.14
  • Accepted : 2010.09.30
  • Published : 2010.11.20
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Abstract

Ruthenium catalysts modified by selenium have been introduced as alternative materials to Pt in Direct methanol fuel cells (DMFCs). RuSe nano-particles were synthesized on the Vulcan XC72R carbon supports via polyol method. The prepared catalysts were electrochemically and physically characterized by cyclic voltammetry (CV,) linear sweep voltammetry, methanol tolerance test, X-ray diffraction (XRD), Transmission electron microscopy (TEM), Energydispersive Spectrometer (EDS) and X-ray photoelectron spectroscopy (XPS). Increasing the Se concentration up to 20 at % increased the electro-catalytic activity for the oxygen reduction. By increasing Se amount, Ru metallic form on the surface was increased. The $Ru_{80}Se_{20}$/C catalysts showed the highest oxygen reduction reaction (ORR) activity and outstanding methanol tolerant property in half cell tests as well as single cell test.

Keywords

References

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