상하수도학회지 (Journal of Korean Society of Water and Wastewater)

  • 제24권4호
  • /
  • Pages.463-474
  • /
  • 2010
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  • 1225-7672(pISSN)
  • /
  • 2287-822X(eISSN)
대한상하수도학회 (The Korean Society of Water and Wastewater)
권호 표지

하수의 화학적 응집조건 및 응집제별 응집효율 분석

Chemical Coagulation Conditions and Efficiency of Sewage with Al(III) and Fe(III) Coagulants

  • 박준규 (충북대학교 환경공학과) ;
  • 전동걸 (충북대학교 환경공학과) ;
  • 박노백 (농촌진흥청 국립농업과학원) ;
  • 전항배 (충북대학교 환경공학과)
  • 투고 : 2009.08.25
  • 심사 : 2010.08.13
  • 발행 : 2010.08.15
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초록

In this study, chemical coagulation conditions for treating combined sewer overflow(CSO) occurred during rainy season were evaluated by jar tests with aluminum sulfate[$Al_2(SO_4)_3{\cdot}17H_2O$] and ferric chloride[$FeCl_3{\cdot}6H_2O$]. The raw domestic sewage sampled from the primary sedimentation tank at a local sewage treatment plant was filtered through $150{\mu}m$ sieve before using. Point of zero charge(PZC) for various dose of aluminum sulfate occurred at pH 5.8-6.5, while for ferric chloride occurred at pH 5.3-6.0 in term of streaming current(SC) values. Charge neutralization ability of aluminum sulfate was bigger than that of ferric chloride. Optimum pH and dose of aluminum sulfate and ferric chloride were 6.2, 0.438mM and 5.8, 0.925mM, respectively. Removal efficiencies of TCOD, turbidity, SS and TP were 75, 97, 95, 96% with aluminum sulfate and 74, 96, 98, 99% with ferric chloride at their optimum coagulation conditions. More efficient removal of SS, TP and small particles was possible with ferric chloride at optimum coagulation conditions. Both SC values and COD removal started to increase where soluble phosphorus was completely removed.

키워드

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