Properties of Ge,Ga and Ga-doped ZnO thin films prepared by RF magnetron sputtering

RF magnetron sputtering으로 생성한 Ga,Ge와 Ga이 도핑된 ZnO 박막의 특성

  • Received : 2010.08.18
  • Accepted : 2010.09.15
  • Published : 2010.09.30

Abstract

The ZnO thin films doped with Ga(GZO) and both Ga and Ge(GZO:Ge) were deposited on glass substrate by using RF sputtering system respectively. Structural, morphological and optical properties of the films deposited in the same condition were investigated. Structural properties of the films were investigated by Field Emission Scanning Electron Microscopy, FE-SEM images and X-ray diffraction, XRD analysis. These studies showed shape of films' surface and direction of film growth respectively. It's showed that all films were deposited by vertical orientation strongly. It can be confirmed that all dopants of targets were included in deposited films by results of EDX analysis. UV-Vis spectrometer results showed that all samples had highly transparent characteristics in visible region and have similar 3.28~3.31 eV band gap. It was found that existence of all dopants by EDX analysis. Morphology and roughness of surface of each film were clearly shown by Atomic Force Microscopy, AFM images. It was found in this research that film doped with Ge more dense and stable with hardly any difference in gap energy compared to ZnO films.

Keywords

References

  1. Z.A. Wang, J.B. Chu, H.B. Zhu, Z. Sun, Y.W. Chen, S.M. Huang, "Growth of ZnO:Al films by RF sputtering at room temperature for solarcell applications", Solid-State Electronics 53 (2009) 1149-1153 https://doi.org/10.1016/j.sse.2009.07.006
  2. F. Wu, L. Fang, Y.J. Pan, K. Zhou, L.P. Peng, Q.L. Huang, C.Y. Kong, "Seebeck and magnetoresistive effects of Ga-doped ZnO thin films prepared by RFmagnetron sputtering", Applied Surface Science 255 (2009) 8855-8859 https://doi.org/10.1016/j.apsusc.2009.06.076
  3. Yu-ri Choi, Il-Hyun Jung "ZnO Nanostructure Characteristics by VLS Synthesis", J. Korean Ind. Eng. Chem., Vol.20, No.6, December 2009,617-621.
  4. Chen Y, Bagnall DM, Koh HJ, Park KT, Hiraga K, Zhu Z, et al. J Appl Phys,.84 ,3912(1988).
  5. Il-Hyun Jung, Myung-Sic Chae, Ui-Am Lee, "Synthesis and optical properties of star-like ZnO nanostructures grown on with carbon catalyst", Journal of the Semiconductor & Display Thechnology, Vol. 9, No.2. June 2010
  6. Jung-Min Kim, P. Thiyagarajan, Shi-Woo Rhee, "Deposition of Al-doped ZnO films on polyethylene naphthalate substrate with radio frequency magnetron sputtering", Thin Solid Films 518 (2010) 5860-5865 https://doi.org/10.1016/j.tsf.2010.05.098
  7. Won-Jun Cho, Seong-Jun Kang, and Yung-Sup Yoon, "Effects of The Substrate Temperature and The Thin film Thickness on The Properties of The Ga-doped ZnO Thin Film", Journal of Semiconductor Technology and Science, Vol 47 SD Issue 1, pp.6-13
  8. Seung-Wook Shin, Kyu-Ung Sim, Jong-Ha Moon, Jin Hyeok Kim, "The effect of processing parameters on the properties of Ga-doped ZnO thin films by RF magnetron sputtering", Current Applied Physics Volume 10, Issue 2, Supplement 1, March 2010, Pages S274-S277 https://doi.org/10.1016/j.cap.2009.11.060
  9. K.U. Sim et al., Effects of dopant (Al, Ga, and In) on the characteristics of ZnO thin films prepared by RF magnetron sputtering system, Curr. Appl. Phys. (2010), doi:10.1016/j.cap.2010.02.028
  10. D.H. Fan, Z.Y.Ning, M.F. Jiang "Characteristics and luminescence of Ge doped ZnO films prepared by alternate radio frequency magnetron sputtering", Applied Surface Science 245 (2005) 414-419 https://doi.org/10.1016/j.apsusc.2004.10.037
  11. Meifu Jiang , Zhenning Wang, Zhaoyuan Ning, "Study of structural and optical properties of Ge doped ZnO films", Thin Solid Films 517 (2009) 6717-6720 https://doi.org/10.1016/j.tsf.2009.05.027
  12. Semelius, B. E., Berggren, K. F., Jin, Z. C., Hamberg,I., Granqvist, C. G. "Band gap tailoring of AZO bymeans of heavy Al doping", Phys. Rev. B, Vol. 37,pp. 10244-10248, 1988. https://doi.org/10.1103/PhysRevB.37.10244