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Conversion of Vegetable Oils and Mixed Fat into Biodiesel Using $Al_2O_3$-Supported CaO Catalyst

$Al_2O_3$ 지지 CaO촉매에 의한 식물유와 혼합지방의 바이오디젤화

  • Hyun, Young-Jin (Department of Chemical & Life Science Engineering, Jeju Nation'l University)
  • 현영진 (제주대학교 공과대학, 생명화학공학과)
  • Received : 2010.09.27
  • Accepted : 2010.12.06
  • Published : 2010.12.31

Abstract

The transesterification of rapeseed oil, soybean oil, and mixed fat were conducted at $65^{\circ}C$ with $Al_2O_3$-supported CaO, 0.8 wt% KOH, 1 wt% NaOH and mixed catalyst. The overall conversion(%) of rapeseed oil indicated to be 96% at the 12:1 molar ratio of methanol to oil, 8 wt% CaO and 2 wt% water. The pH ranges of biodiesel for mixed fat using four catalysts and for three fats using 8wt% CaO were 7.3-9.1, 7.3-7.5, respectively. The volumes of water needed to wash biodiesel from rapeseed oil using 0.8 wt% KOH and 8 wt% CaO were 15 mL and 3 mL.

Keywords

References

  1. J. Zhang, S. Chen and Y. Yan, Biodiesel production from vegetable oil using heterogenous acid and alkali catalyst, Fuel, 89, 2939 (2010). https://doi.org/10.1016/j.fuel.2010.05.009
  2. A. Alba-Rubio,, J. Meride-Robbles and R. Moreno-Tosto, Heterogenous transesterification process by using CaO supported on zinc oxide as basic catalysts, Catalysis Today, 149, 285 (2010).
  3. Xie W. L., Peng H. and Chen L. G., Transesterification of soybean oil catalyzed by potassium loaded on alumina as a solid-base catalyst, Appl. Cata. A, 300, 67 (2006). https://doi.org/10.1016/j.apcata.2005.10.048
  4. Suppes G. J, Dasari M. A. and Doskoul E. J., Transesterification of soybean oil with zeolite and metal catalysts, Appl. Cata. A, 257, 213 (2004). https://doi.org/10.1016/j.apcata.2003.07.010
  5. Z. Yang, and W. Xie, Soybean oil transesterification over zinc oxide modified with alkali earth metal, Fuel Processing Technology, 88, 631 (2007). https://doi.org/10.1016/j.fuproc.2007.02.006
  6. M. Zabeti, W. Daud and M. K. Aroua, Otimization of the activity of $CaO/Al_2O_3$ catalyst for biodiesel production using response surface methodology, Applied Catalysis A, General, 366, 154 (2009). https://doi.org/10.1016/j.apcata.2009.06.047
  7. Zabeti H.and Aroua M. K., Activity of solid catalysts for biodiesel production : A review, Fuel Processing Technology, 90, 770 (2009). https://doi.org/10.1016/j.fuproc.2009.03.010
  8. M. Zabeti, W. M. Daud and M. K. Arouse, Biodiesel production using alumina-supported calsium oxide : An optimization study, Fuel Processing Technology, 91, 243 (2010). https://doi.org/10.1016/j.fuproc.2009.10.004
  9. X. Liu, H. He and X. Piao, Trasesterification of soybean oil to biodiesel using CaO as a solid base catalysts, Fuel, 87, 216 (2008). https://doi.org/10.1016/j.fuel.2007.04.013
  10. X. Liu, Y. Wang, and S. Zhu, Calcium methoxide as a solid catalyst for the transesterificarion of soybean oil to biodiesel with methanol, Fuel, 87, 1076 (2008). https://doi.org/10.1016/j.fuel.2007.05.059
  11. Gryglewicz S., Rapeseed oil methyl esters preparation using heterogenous catalysts, Bioresour. Technol., 70, 248 (1999).
  12. S. Gryglewicz, Rapeseed oil methyl esters preparation using heterogenous catalysis, Bioresources Technology, 70, 249 (1999). https://doi.org/10.1016/S0960-8524(99)00042-5
  13. V. Veljkovic, Z. Todorovic and T. Skala, Kinetics of sunflower oil methanolysis catalyzed by calcium oxide, Fuel, 88. 1554 (2009). https://doi.org/10.1016/j.fuel.2009.02.013
  14. Granados M. L., Martin A. D. and Cabelo G. F., Biodiesel from sunflower oil by using activated calcium oxide, Appl. Catal. B, 73, 327 (2007) https://doi.org/10.1016/j.apcatb.2007.01.005
  15. Z. Helwani, J. Kim and J. Fernando, Soild heterogenous catalysts for transesterification of triglycerides with methanol : A review, Appl. Catal. A, 363, 1 (2009). https://doi.org/10.1016/j.apcata.2009.05.021
  16. M. Kouzu, M. Tajika and J. Hidaka, Calcium oxide as a solid base catalyst for transesterification of soybean oil and its application to biodiesel production, Fuel, 87, 2798 (2008). https://doi.org/10.1016/j.fuel.2007.10.019
  17. H. Hattori, Heterogenous basic catalysis, Chem. Rev. 95, 537 (1995). https://doi.org/10.1021/cr00035a005