Bulletin of the Korean Chemical Society

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Efficient Synthetic Method of Z-Selective 2-Halo-1,3-dienes from Reactions of Allenols Possessing Ethoxycarbonyl and Vinyl Group with Indium Trihalide

  • Eom, Da-Han (Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University) ;
  • Kim, Sung-Hong (Analysis Research Division Daegu Center, Korea Basic Science Institute) ;
  • Lee, Phil-Ho (Department of Chemistry and Institute for Molecular Science and Fusion Technology, Kangwon National University)
  • Published : 2010.03.20
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Abstract

An efficient synthetic method of Z-selective 3-ethoxycarbonyl-2-halo-1,3-dienes and 3-vinyl-2-halo-1,3-dienes was developed from the reaction of allenols having ethoxycarbonyl and vinyl group with indium trihalides at room temperature in $CH_2Cl_2$.

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References

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