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Effects of Seed Layer and Thermal Treatment on Atomic Layer Deposition-Grown Tin Oxide

  • Received : 2010.07.07
  • Accepted : 2010.09.03
  • Published : 2010.10.31

Abstract

The preparation of tin oxide thin films by atomic layer deposition (ALD), using a tetrakis (ethylmethylamino) tin precursor, and the effects of a seed layer on film growth were examined. The average growth rate of tin oxide films was approximately 1.2 to 1.4 A/cycle from $50^{\circ}C$ to $150^{\circ}C$. The rate rapidly decreased at the substrate temperature at $200^{\circ}C$. A seed effect was not observed in the crystal growth of tin oxide. However, crystallinity and the growth of seed material were detected by XPS after thermal annealing. ALD-grown seeded tin oxide thin films, as-deposited and after thermal annealing, were characterized by X-ray diffraction, atomic force microscopy and XPS.

Keywords

References

  1. C. Jin, T. Yamazaki, K. Ito, T. Kikuta, and N. Nakatani, Vacuum 80, 723 (2006) [DOI: 10.1016/j.vacuum.2005.11.002].
  2. R. D. Tarey and T. A. Raju, Thin Solid Films 128, 181 (1985) [DOI: 10.1016/0040-6090(85)90070-7].
  3. M. Adnane, H. Cachet, G. Folcher, and S. Hamzaoui, Thin Solid Films 492, 240 (2005) [DOI: 10.1016/j.tsf.2005.06.085].
  4. J. W. Elam, D. A. Baker, A. J. Hryn, A. B. F. Martinson, M. J. Pellin, and J. T. Hupp, J Vac. Sci. Technol. A 26, 244 (2008) [DOI: 10.1116/1.2835087].
  5. W. Lee, Y. Choi, K. Hong, N. H. Kim, Y. Park, and J. Park, J. Korean Phys. Soc. 46, L756 (2005).
  6. J. Sundqvist, J. Lu, M. Ottosson, and A. Harsta, Thin Solid Films 514, 63 (2006) [DOI: 10.1016/j.tsf.2006.02.031].
  7. J. D. Ferguson, K. J. Buechler, A. W. Weimer, and S. M. George, Powder Technol. 156, 154 (2005) [DOI: 10.1016/j.powtec.2005.04.009].
  8. W. S. Choi, Trans. Electr. Electron. Mater. 10, 200 (2009) DOI:10.4313/TEEM.2009.10.6.200].
  9. V. E. Henrich, Rep. Prog. Phys. 48, 1481 (1985) [DOI: 10.1088/0034-4885/48/11/001]
  10. J. F. Moulder and J. Chastain, Handbook of X-Ray Photoelectron Spectroscopy: A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data (Physical Electronics Division Perkin-Elmer Corp., Eden Prairie, 1992).
  11. J. Lu, J. Sundqvist, M. Ottosson, A. Tarre, A. Rosental, J. Aarik, and A. Harsta, J. Cryst. Growth 260, 191 (2004) [DOI: 10.1016/j.jcrysgro.2003.08.042].

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