Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Effect of Bimetallic Pt-Rh and Trimetallic Pt-Pd-Rh Catalysts for Low Temperature Catalytic Combustion of Methane

  • Bhagiyalakshmi, Margandan (Chemical Engineering Department, Hanseo University) ;
  • Anuradha, Ramani (Chemical Engineering Department, Hanseo University) ;
  • Park, Sang-Do (Carbon Dioxide Reduction & Sequestration Research Center, Korea Institute of Energy Research) ;
  • Park, Tae-Sung (Carbon Dioxide Reduction & Sequestration Research Center, Korea Institute of Energy Research) ;
  • Cha, Wang-Seog (School of Civil and Environ., Kunsan National University) ;
  • Jang, Hyun-Tae (Chemical Engineering Department, Hanseo University)
  • Published : 2010.01.20
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Abstract

Monometallic, bimetallic and trimetallic particles consisting of different weight compositions of Pt-Pd-Rh over pure alumina wash coats have been synthesized and their catalytic performance on methane conversion was studied from 150 to $600^{\circ}C$. Different catalyst formulations with variable Pt, Pd and Rh contents for bimetallic and trimetallic systems were tried and $Pt_{(1.5)}Rh_{(0.3)}/Al_2O_3$ and $Pt_{(1.0)}Pd_{(1.0)}Rh_{(0.3)}/Al_2O_3$ shows low $T_{50}$ and $T_{90}$ temperatures. Bimetallic and trimetallic particle synergism acts as three way catalysts and therefore, all the catalysts show 100% methane conversion. The effect of supports such as $ZrO_2$ and $TiO_2$ on methane combustion was investigated; from $T_{50}$ and $T_{90}$ results both $Al_2O_3$ and $ZrO_2$ are suitable supports for low temperature methane combustion.

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