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Effect of Monobutyl Tinoxide Catalyst in Esterification Reaction between Succinic Acid and 1,4-butanediol

Succinic Acid과 1,4-butanediol간의 에스테르화반응에서 Monobutyl Tinoxide 촉매의 영향

  • Park, Keun-Ho (Dept of Chemical Engineering, Changwon National University) ;
  • Kim, Duck-Sool (Dept. of Biomedical Engineering, Tongmyong University)
  • 박근호 (창원대학교 화공시스템공학과) ;
  • 김덕술 (동명대학교 의용공학과)
  • Published : 2009.09.30

Abstract

Esterification reaction between succinic acid and 1,4-butanediol was kinetically investigated in the presence of monobutyl tinoxide catalysts at $150{\sim}190^{\circ}C$. The reaction rates measured by the amount of distilled water from the reaction vessel. The esterification reaction was carried out under the first order conditions with respect to the concentration of reactants, respectively. The overall reaction order was 2nd. The linear relationship was shown between apparent reaction rate constant and reciprocal absolute temperature. By the Arrhenius plot the activation energy have been calculated as 87.567 kJ/mol under monobutyl tinoxide catalyst and also apparent reaction rate constant, k' was found to obey first kinetics with respect to the concentration of catalyst.

Keywords

References

  1. E. H. Woo, J. W. Barlow. and D. R. Paul, Phase behavior of blends of aliphatic polyesters with a vinylidene chloride/vinyl chloride copolymer, J. Appl. Polym Sci., 32, 3889 (1986) https://doi.org/10.1002/app.1986.070320308
  2. W. L. Chang, T. Baranowski, and T. Karalis, Role of functionality in MDI-based elastomer preparation, J. Polym Chem Ed 51 (6). 1077 (1993) https://doi.org/10.1002/app.1994.070510614
  3. S. S. Park and J. S. Choi, Kinetics of the Formation of Poly(ethylene-co-I,4-cyclohexylenedimethylene)Terephthalate Oligomer by Various Catalysts, Korean Chem Eng. Res., 42(3), 326 (2004)
  4. B. Belhalfaoui, A. Aziz, E. H. Elandaloussi, M. S. Ouali, and L. C. De Menorval, Succinate-bonded cellulose: A regenerable and powerful sorbent for cadmium-removal from spiked highhardness groundwater, J. hazard mater .. 169(1), 831 (2009) https://doi.org/10.1016/j.jhazmat.2009.04.021
  5. B. V. Ahn, S. H. Kim, Y. H. Kim, and j. S. Yang, Synthesis and characterization of the biodegradable copolymers from succinic acid and adipic acid with l,4-butanediol, J. Appl. Polym Sci., 82(11), 2808 (2001) https://doi.org/10.1002/app.2135
  6. K. H. Park, and N. H. Kim, A Study on the Transesterification Reaction between Dimethylphthalate and l,4-butanediol, Transaction of the institute of industry and technology, 13, 211 (1999)
  7. R. U. Lemieux and A. G. Mclnes, The Preparation of Sucrose Monoesters, Can J. chem, 40, 2376 (1962) https://doi.org/10.1139/v62-362
  8. K. H. Park, Effect of Chloride Catalysts in Transesterification Reaction between Dimethylphthalate and Ethylene Glycol, Transaction of the institute of industry and technology, 12, 307 (1998)
  9. R. Nava, T. Halachev, and R. Rodriguez, Immobilized zinc acetate complex on the surface of silica-alumina gel modified by succinic acid: an efficient catalyst for the esterification of DMT, Micropo. Mesopo. Mater. : Offici. J Inter. Zeolite Asso.. 7(2), 91 (2005) https://doi.org/10.1016/j.micromeso.2004.09.021
  10. R. Bacaloglu, M. Fisch, and K. Biesiada, Kinetics of polyesterification of adipic acid with 1,3-butanediol, Polym Eng. Sci., 38(6), 1014 (1998) https://doi.org/10.1002/pen.10268
  11. A. K. Kolah, N. S. Asthana, D. T. Vu, C. T. Lira, and D. J. Miller, Reaction Kinetics for the Heterogeneously Catalyzed Esterification of Succinic Acid with Ethanol, Ind Eng. Chem Res., 47, 5313 (2008) https://doi.org/10.1021/ie0706616
  12. J. H. Clark, V. Budarin, T. Dugmore, R. Luque, D.J. Macquarrie, and V. Strelko, Catalytic performance of carbonaceous materials in the esterification of succinic acid, Catalysis Communications, 9(8), 1709 (2008) https://doi.org/10.1016/j.catcom.2008.01.037
  13. Y. X. Xu, j. Xu, D. Liu, B. Guo, and X. Xie, Synthesis and Characterization of Biodegradable Poly(butylene Succinateco- Propylene Succinate)s, J. Appl. Polym Sci., 109(3), 1881 (2008) https://doi.org/10.1002/app.24544
  14. S. S. Park, H. W. Jun, and S, S, Im, Kinetics of Forming Poly (Butylene Succinate) (PBS) Oligomer m the Presence of lVlBTO Catalyst. Polymer Eng. and Sci., 38(6), 905 (1998) https://doi.org/10.1002/pen.10257
  15. K. H. Park, The Effect of Anion Catalyst in Transesterification Reaction", J. Kor. Oil Chem Soc., 9(2), 141 (1992)
  16. K. H. Park and B. C. Shon, The Effect of Nitrate Catalyst in Transesterification Reaction between Dimethylphthalate and Ethylene Glycol, J. Kor. Oil Chem Soc., 10(1), 23 (1993)