한국수소및신에너지학회논문집 (Journal of Hydrogen and New Energy)

  • 제20권1호
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  • Pages.55-63
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  • 2009
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  • 1738-7264(pISSN)
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  • 2288-7407(eISSN)
한국수소및신에너지학회 (The Korean Hydrogen and New Energy Society)
권호 표지

시베리아산 전나무 바이오매스의 아세톤 용매분해반응

Acetone Solvolysis of a Siberian Spruce Biomass

  • 윤성욱 (단국대학교 공학교육혁신센터)
  • Yoon, Sung-Wook (Innovation Center for Engineering Education, Dankook Univ.)
  • 발행 : 2009.02.28
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초록

In this study, thermochemical degradation by acetone solvolysis reaction of siberian spruce wood was investigated for a temperature range of $200{\sim}400^{\circ}C$. The liquid products by acetone solvolysis from siberian spruce wood produced various kinds of aliphatics, cyclic compounds and aromatics included phenols etc. Combustion heating value of liquid products by acetone solvolysis conversion processes was in the range of $8,010{\sim}8,180cal/g$. The energy yield in acetone solvolysis of siberian spruce wood was as high as 74.2% after 40min of reaction at $400^{\circ}C$. The liquid products from the thermochemical conversion of siberian spruce wood could be used as high-octane-value fuels and fuel additives.

키워드

참고문헌

  1. Donald L. Klass, Biomass for Renewable Energy, Fuels, and Chemicals, Academic Press, 1998
  2. E. Poitrat and G. Gosse, 'Liquid fuels in France ; Experiments and commercial application', Proc. of Euro. Energy Crop Confer., 1996, Enschede, Netherland
  3. Dinesh Mohan, Charles Pittman, Philip Steele, Pyrolysis of Wood/Biomass for Bio-oil: Critical Review, Energy & Fuels, Vol. 20, No. 3, pp. 848-889, 2006 https://doi.org/10.1021/ef0502397
  4. M. Olazar, R. Aguado, and J.Bilbao, 'Pyrolysis of Biomass in a Jet Spouted Bed Reactor', Bioresource Technology, Vol. 60, 1997, pp. 51-58 https://doi.org/10.1016/S0960-8524(96)00170-8
  5. F. A. Agblevor, S. Besler, and A. E. Wieselogel, 'Fast Pyrolysis of Stored Biomass Feedstocks' Energy and Fuels, Vol. 9, 1995, pp. 635-640 https://doi.org/10.1021/ef00052a010
  6. Huber, G. W., S. Iborra, A. Corma, 'Synthesis of transportation fuels frombiomass : Chemistry, catalysists, and engineering' Chemical Reviews. Vol. 106, 2006, pp. 4044-4098 https://doi.org/10.1021/cr068360d
  7. S. Czernik, A. Bridgwater, 'Overview of Applications of Biomass Fast Pyrolysis Oil', Energy & Fuels, Vol. 18(2), 2004, pp. 590-598 https://doi.org/10.1021/ef034067u
  8. D. Mohan, C. Pittman, and P. Steele, 'Pyrolysis of Wood/Biomass for Bio-oil: Critical Review', Energy & Fuels, Vol. 20(3), 2006, pp. 848-889 https://doi.org/10.1021/ef0502397
  9. Anthony V. Bridgwater, 'Biomass Fast Pyrolysis', Thermal Science, Vol. 8(2), 2004, pp. 21-49 https://doi.org/10.2298/TSCI0402021B
  10. 윤성욱, '시베리아산 전나무 바이오매스의 열분해-액화반응', 한국수소 및 에너지 학회 논문집, Vol. 19(5), 2008, pp. 430-448
  11. Sung-Wook Yoon, Jong-Jib Lee and Byung-Hak Lee, 'Production of Fuels in Solvilysis from Cellulose', KSEE, Vol. 26(12), 2004, pp. 1312-1318
  12. A. Demirbas, 'Mechanisms of Liquefaction and Pyrolysis Reaction of Biomass', Energy Conversion and Management, Vol. 41, 2000, pp. 633-6463 https://doi.org/10.1016/S0196-8904(99)00130-2
  13. J.P. Andre, 'Cell and Molecular Biology of Wood Formation' BIOS Scientific Publisher. 2000, pp. 387-395
  14. A. Demirbas, 'Yields of Oil Products from Thermochemical Biomass Conversion Processes', Energy Convers. Mgmt., Vol. 39(7), 1998, pp. 685-690 https://doi.org/10.1016/S0196-8904(97)00047-2
  15. 이선영, '바이오매스로부터 연료 및 화학원료 생성', 산림정보, Vol. 5, 1999, pp. 117-119
  16. 홍성구, '바이오매스의 활용전략', 농어촌과 환경, Vol. 95, 2008, pp. 15-32