한국세라믹학회지 (Journal of the Korean Ceramic Society)

  • 제46권6호
  • /
  • Pages.574-582
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  • 2009
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  • 1229-7801(pISSN)
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  • 2234-0491(eISSN)
한국세라믹학회 (The Korean Ceramic Society)
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변형 Sol-Gel 방법을 이용한 고온가스로 핵연료 미세구입자 제조

HTGR Nuclear Fuel Microsphere Preparation Using the Modified Sol-Gel Method

  • 정경채 (한국원자력연구원 피복입자 핵연료기술개발과제) ;
  • 김연구 (한국원자력연구원 피복입자 핵연료기술개발과제) ;
  • 오승철 (한국원자력연구원 피복입자 핵연료기술개발과제) ;
  • 조문성 (한국원자력연구원 피복입자 핵연료기술개발과제)
  • 발행 : 2009.11.30
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초록

$UO_2$ microsphere particles, core material of HTGR(High Temperature Gas Reactor) nuclear fuel, were prepared using by the GSP(Gel Supported Precipitation) method which is a modified-method of the wet sol-gel process. The spherical shape of initial liquid ADU droplets from the vibration nozzle system was continuously kept till the conversion to the final $UO_2$ microsphere. But the size of a final $UO_2$ microsphere was shrunken to about 25% of an initial ADU droplet size. Also, we found that the composition of dried-ADU gel particles was constituted of the very complicated phases, coexisted the U=O, C-H, N-H, N-O, and O-H functional groups by FT-IR. The important factors for obtain the no-crack $UO_2$ microsphere during the thermal treatment processes must perfectly wash out the remained-$NH_4NO_3$ within the ADU gel particle in washing process and the selections of an appropriate heating rate at a suitable gas atmosphere, during the calcining of ADU gel particles, the reducing of $UO_3$ particles, and the sintering of $UO_2$ particles, respectively.

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