Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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The Rapid and Efficient Synthesis of Bromohydrins from Olefins under HBr/H2O2 System by Visible Light Induced

  • Tang, Rui-Ren (School of Chemistry and Chemical Engineering, Central South University) ;
  • Gong, Nian-Hua (School of Chemistry and Chemical Engineering, Central South University)
  • Published : 2009.08.20
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Abstract

A simple and safe method has been presented for conversion of olefins into bromohydrins using hydrogen bromide and hydrogen peroxide as bromide source by visible light induced within a very short time to get high yield bromohydrins along with a little mount dibromo-product. In this paper, cyclohexene is firstly carried out as the model substrate and investigated the bromination under HBr/$H_2O_2$ system using 150 W incandescent light irradiated in C$Cl_4$ within short time to get good yield of 2-bromocyclohexanol along with a little mount of 1,2-dibromocyclohexane; then, a series of alkenes are brominated to corresponding bromohydrins using the same protocol.

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References

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