Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Structure Analysis of α and β Forms of [12] Metallacrown-6 Nickel(II) Complex: [Ni6(SCH2CH2CH3)12]

  • Xiao, Hai Lian (College of Materials Science and Engineering, Qingdao University of Science and Technology) ;
  • Jian, Fang Fang (New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology) ;
  • Zhang, Ke Jie (Nanjing University of Science and Technology)
  • Published : 2009.04.20
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Abstract

Two modifications of the ${\alpha}\;and\;{\beta}$ forms of propyl mercaptan nickel(II) cluster, [$Ni_6(SCH_2CH_2CH_3)_{12}$], have been synthesized and their crystal structures have been determined by single-crystal X-ray diffraction. The alkyl groups are away from $Ni_6$ ring in $\alpha$ form whereas they are near to the Ni atom in $\beta$ form. The distance of Ni-H in $\beta$ form [2.576(5) $\AA$] is much shorter than that in $\alpha$ form [3.101(2) $\AA$]. In the crystal lattice of $\beta$ form, the whole structure forms a flower shape.

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References

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