Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Variation in IR and Raman Spectra of CD3CN upon Solvation of InCl3 in CD3CN: Distinctive Blue Shifts, Coordination Number, Donor-Acceptor Interaction, and Solvated Species

  • Published : 2009.04.20
Download PDF
⟨ Previous Next ⟩

Abstract

Notable blue shifts of the ν2 $C{\equiv}N$ stretching, $_{v4}$ C-C stretching and $_{v8}$ CCN deformation bands of $CD_3CN$ are observed upon solvation of $InCl_3$, resulting from the donor-acceptor interaction. The Raman spectrum in the $_{v2}$ region shows further details; at least two new bands emerge on the blue side of the $_{v2}$ band of free $CD_3CN$, whose relative intensities vary with concentration, suggesting that there exist at least two different cationic species in the solution. The strong hydrogen bonds formed between the methyl group and ${InCl_4}^-$ result in a large band appearing on the red side of the ν1 $CD_3$ symmetric stretching band. The solvation number of $InCl_3$, determined from the Raman intensities of the $C{\equiv}N$ stretching bands for free and coordinated $CD_3CN$, increases from $\sim$1.5 to $\sim$1.8 with decreasing concentration.

Keywords

References

  1. Jamros, D.; Wojcik, M.; Lindgren, J.; Stangret, J. J. Phys. Chem. B 1997, 101, 6758. https://doi.org/10.1021/jp9710998
  2. Jamros, D.; Wojcik, M.; Lindgren, J. Spectrochim. Acta A 2000, 56, 1939. https://doi.org/10.1016/S1386-1425(00)00258-4
  3. Nyquist, R. A. Appl. Spectrosc. 1990, 44, 1405. https://doi.org/10.1366/000370290789619649
  4. Dimitrova, Y. J. Mol. Struct. 1995, 343, 25. https://doi.org/10.1016/0166-1280(95)90517-0
  5. Saito, T.; Yamakawa, M.; Taksuka, M. J. Mol. Spectrosc. 1981, 90, 359. https://doi.org/10.1016/0022-2852(81)90133-8
  6. Bertie, J. E.; Lan, Z. J. Phys. Chem. B 1997, 101, 4111. https://doi.org/10.1021/jp9639511
  7. Hoskins, A. R.; Edwards, H. G. M.; Johnson, A. F. J. Mol. Struct. 1991, 263, 1. https://doi.org/10.1016/0022-2860(91)80050-E
  8. Gutmann, V.; Resch, G.; Linert, W. Coord. Chem. Rev. 1982, 43, 133. https://doi.org/10.1016/S0010-8545(00)82094-9
  9. Vijay, A.; Sathyanarayana, D. N. J. Phys. Chem. 1996, 100, 75. https://doi.org/10.1021/jp9431548
  10. Cho, H.-G.; Cheong, B.-S. J. Mol. Struct. (Theochem) 2000, 496, 185. https://doi.org/10.1016/S0166-1280(99)00183-9
  11. Fawcett, W. R.; Liu, G.; Faguy, P. W.; Foss, C. A., Jr.; Motheo, A. J. J. Chem. Soc. Faraday Trans. 1993, 89, 811. https://doi.org/10.1039/ft9938900811
  12. Fawcett, W. R.; Liu, G. J. Phys. Chem. 1992, 96, 4231. https://doi.org/10.1021/j100190a025
  13. Oliver, B. G.; Janz, G. J. J. Phys. Chem. 1970, 74, 3819. https://doi.org/10.1021/j100715a017
  14. Cha, J.-N.; Cheong, B.-S.; Cho, H.-G. J. Phys. Chem. A 2001, 105, 1789. https://doi.org/10.1021/jp003751w
  15. Seo, J.-S.; Cheong, B.-S.; Cho, H.-G. Spectrochim. Acta A 2002, 58, 1747. https://doi.org/10.1016/S1386-1425(01)00636-9
  16. Seo, J.-S.; Kim, K.-W.; Cho, H.-G. Spectrochim. Acta A 2003, 59, 477. https://doi.org/10.1016/S1386-1425(02)00190-7
  17. Cho, H.-G. Spectrochim. Acta A 2003, 59, 1517. https://doi.org/10.1016/S1386-1425(02)00356-6
  18. Fawcett, W. R.; Liu, G.; Kessler, T. E. J. Phys. Chem. 1993, 97, 9293. https://doi.org/10.1021/j100139a007
  19. B$\ddot{o}$ck, S.; N$\ddot{o}$th, H.; Wietelmann, A. Z. Naturforsch. 1990, 45B, 979.
  20. Greenwood, N. N.; Wade, K. J. Chem. Soc. 1958, 1663. https://doi.org/10.1039/jr9580001663
  21. Schmulbach, C. D.; Ahmed, I. Y. Inorg. Chem. 1971, 10, 1902. https://doi.org/10.1021/ic50103a013
  22. Ahmed, I. Y.; Schmulbach, C. D. Inorg. Chem. 1972, 11, 228. https://doi.org/10.1021/ic50108a003
  23. Atkinson, A. W.; Chardwick, J. R.; Kinsella, E. J. Inorg. Nucl. Chem. 1968, 30, 401. https://doi.org/10.1016/0022-1902(68)80466-X
  24. Dalibart, M.; Derouault, J.; Granger, P.; Chapelle, S. Inorg. Chem. 1982, 21, 1040. https://doi.org/10.1021/ic00133a034
  25. Beattie, I. R.; Jones, R. J.; Howard, J. A. K.; Smart, L. E.; Gilmore, C. J.; Akitt, J. W. J. Chem. Soc. Dalton 1979, 528.
  26. Woodward, L. A.; Nord, A. A. J. Chem. Soc. 1956, 3721. https://doi.org/10.1039/jr9560003721
  27. Cho, J.-S.; Cho, H.-G. J. Kor. Chem. Soc. 2007, 51, 287 https://doi.org/10.5012/jkcs.2007.51.3.287
  28. Clarke, J. H. R.; Hester, R. E. J. Chem. Phys. 1969, 50, 3106. https://doi.org/10.1063/1.1671513
  29. Jurgens, R.; Alml$\ddot{o}$f, J. Chem. Phys. Lett. 1991, 176, 263. https://doi.org/10.1016/0009-2614(91)90028-8
  30. Ablaeva, M. A.; Zsidomirov, G. M.; Pelmenshchikov, A. G.; Burgina, E. B.; Baltakhinov, V. P. React. Kinet. Catal. Lett. 1992, 48, 569. https://doi.org/10.1007/BF02162709
  31. Miller, J. M.; Onyszchuk, M. Can. J. Chem. 1966, 44, 899. https://doi.org/10.1139/v66-132
  32. Pews, R. G.; Tsuno, Y.; Taft, R. W. J. Am. Chem. Soc. 1967, 89, 2391. https://doi.org/10.1021/ja00986a026
  33. Huggins, C. M.; Pimental, G. C. J. Phys. Chem. 1956, 60, 1615. https://doi.org/10.1021/j150546a004
  34. Glew, D. N.; Rath, N. S. Can. J. Chem. 1971, 49, 837. https://doi.org/10.1139/v71-142
  35. Sadlej, J. Spectrochim. Acta A 1979, 35, 681. https://doi.org/10.1016/0584-8539(79)80129-4
  36. Freedman, T. B.; Nixon, E. R. Spectrochim. Acta A 1972, 28, 1375. https://doi.org/10.1016/0584-8539(72)80107-7
  37. Evans, J. C.; Lo, G. Y.-S. Spectrochim. Acta 1965, 21, 1033. https://doi.org/10.1016/0371-1951(65)80179-5
  38. Jones, D. E. H.; Wood, J. L. J. Chem. Soc. (A) 1971, 3135. https://doi.org/10.1039/j19710003135
  39. Balasubrahmanyam, K.; Janz, G. J. J. Am. Chem. Soc. 1970, 92, 4189. https://doi.org/10.1021/ja00717a009

Cited by

  1. as the Catalytic Species and Answering Why Nonconjugated Dienes Are Generated vol.77, pp.19, 2012, https://doi.org/10.1021/jo301471w
  2. Promoting Terminal Olefin Metathesis with a Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Catalyst vol.130, pp.44, 2018, https://doi.org/10.1002/ange.201808233
  3. Promoting Terminal Olefin Metathesis with a Supported Cationic Molybdenum Imido Alkylidene N-Heterocyclic Carbene Catalyst vol.57, pp.44, 2018, https://doi.org/10.1002/anie.201808233
  4. 아세토니트릴 내에서의 Ag+ 이온의 배위수와 음이온 효과 vol.53, pp.5, 2009, https://doi.org/10.5012/jkcs.2009.53.5.609
  5. Alternative Electrolytes for Li-Ion Batteries Using Glutaronitrile and 2-methylglutaronitrile with Lithium Bis(trifluoromethanesulfonyl) Imide vol.166, pp.14, 2019, https://doi.org/10.1149/2.1261914jes
  6. The DFT Quest for Possible Reaction Pathways, Catalytic Species, and Regioselectivity in the InCl3-Catalyzed Cycloaddition of N-Tosyl Formaldimine with Olefins or Allenes vol.85, pp.5, 2009, https://doi.org/10.1021/acs.joc.9b03309
  7. Power of Infrared and Raman Spectroscopies to Characterize Metal-Organic Frameworks and Investigate Their Interaction with Guest Molecules vol.121, pp.3, 2021, https://doi.org/10.1021/acs.chemrev.0c00487
  8. Mechanism of Ferric Chloride Facilitating Efficient Lithium Extraction from Magnesium-Rich Brine with Tri-n-butyl Phosphate vol.60, pp.23, 2009, https://doi.org/10.1021/acs.iecr.1c01003
  9. On the Role of Dioxane in the Synthesis of In-Derived MOFs vol.21, pp.12, 2009, https://doi.org/10.1021/acs.cgd.1c00766