Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis and Physical Properties of Decylbithiophene End-Capped Oligomers Based on Naphthalene, Anthracene and Benzo[1,2-b:4,5-b']dithiophene

  • Jang, Sang-Hun (Department of Chemistry and Research Institute of Life Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Tai, Truong Ba (Department of Chemistry and Research Institute of Life Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Kim, Min-Kyu (Department of Chemistry and Research Institute of Life Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Han, Jeong-Woo (Department of Chemistry and Research Institute of Life Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Kim, Yun-Hi (Department of Chemistry, Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Shin, Sung-Chul (Department of Chemistry, Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Yoon, Yong-Jin (Department of Chemistry, Research Institute of Natural Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University) ;
  • Kwon, Soon-Ki (School of Nano & Advanced Materials and Enginnering, Gyeongsang National University) ;
  • Lee, Sang-Gyeong (Department of Chemistry and Research Institute of Life Science, Graduate School for Molecular Materials and Nanochemistry, Gyeongsang National University)
  • Published : 2009.03.20
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Abstract

The new candidates for OTFTs, which were composed of naphthalene, anthracene, benzo[1,2-b:4,5-b’]dithiophene and 2-decylbithiophene end-capper were synthesized under Suzuki coupling reaction conditions. All of the oligomers were characterized by FT-IR, mass analysis, UV-vis, PL spectrum, cyclic voltametry (CV), differential scanning calorimetry (DSC), thermal gravimetric analysis (TGA), $^1H-NMR\;and\;^{13}C-NMR$. Investigation of physical properties showed that all of the oligomers have higher oxidation potential and good thermal stability. Especially, DBT-DtB-DBT is soluble in common solvents and suitable for low cost processing technologies.

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References

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