Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Swellable Submicrospheres of Ionic Palladium(II) Complexes Containing Decylmethylbis(m-pyridyl)silane

  • Ryu, Yoon-Kyong (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Kim, Cho-Rong (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Kim, Chi-Won (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Noh, Tae-Hwan (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Jung, Ok-Sang (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
  • Published : 2009.10.20
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Abstract

Ionic palladium(II) complex containing a long aliphatic chain, [(tmeda)$PdL]_2(PF_6)_4$ (tmeda = N,N,N',N'-tetramethylethylenediamine; L = decylmethylbis(m-pyridyl)silane) allowed to form a puckered submicrosphere morphology without any template or additive. The puckered spheres reversibly adsorb and desorb dioxane molecules. Coligand and cosolvent effects on the formation of submicrospherical morphology were observed.

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References

  1. Busch, S.; Dolhaine, H.; DuChesne, A.; Heinz, S.; Hochrein, O.; Laeri, F.; Podebrad, O.; Vietze, U.; Weiland, T.; Knief, R. Eur. J. Inorg. Chem. 1999, 643.
  2. Mann, S. Angew. Chem., Int. Ed. 2000, 39, 3392. https://doi.org/10.1002/1521-3773(20001002)39:19<3392::AID-ANIE3392>3.0.CO;2-M
  3. Yoon, H. J.; Chun, I. S.; Na, Y. M.; Lee, Y.-A.; Jung, O.-S. Chem. Commun. 2007, 492
  4. Chun, I. S.; Kwon, J. A.; Yoon, H. J.; Bae, M. N.; Hong, J.; Jung, O.-S. Angew. Chem., Int. Ed. 2007, 46, 4960. https://doi.org/10.1002/anie.200701152
  5. Chun, I. S.; Lee, K. S.; Hong, J.; Do, Y.; Jung, O.-S. Chem. Lett. 2007, 36, 584. https://doi.org/10.1246/cl.2007.584
  6. Noh, T. H.; Chun, I. S.; Lee, Y.-A.; Ahn, S.; Hong, J.; Jung, O.-S. Bull. Korean Chem. Soc. 2008, 29, 1266. https://doi.org/10.5012/bkcs.2008.29.6.1266
  7. Yoon, H. J.; Chun, I. S.; Kim, J. P.; Lee, Y. S.; Jung, O.-S. Mater. Lett. 2008, 62, 2883. https://doi.org/10.1016/j.matlet.2008.01.064
  8. Kim, S. A.; Kim, J. P.; Ahn, Y. M.; Hong, J.; Jung, O.-S. Bull. Korean Chem. Soc. 2008, 29, 729. https://doi.org/10.5012/bkcs.2008.29.4.729
  9. Xia, Y.; Yang, P.; Sun, Y.; Wu, Y.; Mayers, B.; Gates, B.; Yin, Y.; Kim, F.; Yan, H. Adv. Mater. 2003, 15, 353 https://doi.org/10.1002/adma.200390087
  10. Liu, B.; Zeng, H. C. J. Am. Chem. Soc. 2004, 126, 8124. https://doi.org/10.1021/ja048195o
  11. Cölfen, H.; Mann, S. Angew. Chem., Int. Ed. 2003, 42, 2350. https://doi.org/10.1002/anie.200200562
  12. Vekilov, P.; Christova, C. G.; Dullens, R. P. A.; van Blaaderen, A. Science 2002, 296, 106. https://doi.org/10.1126/science.1067141
  13. Sun, X.; Li, Y. Chem. Eur. J. 2003, 9, 2229. https://doi.org/10.1002/chem.200204394
  14. Li, M.; Schnablegger, H.; Mann, S. Nature 1999, 402, 393. https://doi.org/10.1038/46509
  15. Peng, Q.; Dong, Y.; Li, Y. Angew. Chem., Int. Ed. 2003, 42, 3027. https://doi.org/10.1002/anie.200250695
  16. Shi, T.; Qi, L. M.; Ma, J. M.; Cheng, H. M. J. Am. Chem. Soc. 2003, 125, 3450. https://doi.org/10.1021/ja029958f
  17. Bowden, N.; Terfort, A.; Carbeck, J.; Whitesides, G. M. Science 1997, 276, 233. https://doi.org/10.1126/science.276.5310.233
  18. Gracias, H.; Tien, J.; Breen, T. L.; Hsu, C.; Whitesides, G. M. Science 2000, 289, 1170. https://doi.org/10.1126/science.289.5482.1170
  19. Whitesides, M.; Grzybowski, B. Science 2002, 295, 2418. https://doi.org/10.1126/science.1070821
  20. Thalladi, V. R.; Whitesides, G. M. J. Am. Chem. Soc. 2002, 124, 3520. https://doi.org/10.1021/ja012697+
  21. Kovtyukhova, N. I.; Mallouk, T. E. Chem. Eur. J. 2002, 8, 4355.
  22. Whang, D.; Jin, S.; Wu, Y.; Lieber, C. M. Nano Lett. 2003, 3, 1255. https://doi.org/10.1021/nl0345062
  23. Dinsmore, A. D.; Hsu, M. F.; Nikolaides, M. G.; Marquez, M.; Bausch, A. R.; Weitz, D. A. Science 2002, 298, 1006. https://doi.org/10.1126/science.1074868
  24. Yano, K.; Fukushima, Y. J. Mater. Chem. 2003, 13, 2577 https://doi.org/10.1039/b304867p
  25. Kang, H. J.; Noh, T. H.; Jin, J. S.; Jung, O.-S. Inorg. Chem. 2008, 47, 5528. https://doi.org/10.1021/ic800436n
  26. Dibbern, E. M.; Toublan, F. J.-J.; Suslick, K. S. J. Am. Chem. Soc. 2006, 128, 6540. https://doi.org/10.1021/ja058198g
  27. Yao, Q.; Kinney, E. P.; Zheng, C. Org. Lett. 2004, 6, 2997. https://doi.org/10.1021/ol0486977
  28. Fujita, M.; Ibukuro, F.; Hagihara, H.; Ogura, K. Nature 1994, 367, 720. https://doi.org/10.1038/367720a0
  29. Kang, H. J.; Noh, T. H.; Na, Y. M.; Yoo, K. H.; Jung, O.-S. Inorg. Chim. Acta 2009, 362, 1963. https://doi.org/10.1016/j.ica.2008.09.024
  30. Ryu, Y. K.; Kim, C. R.; Noh, T. H.; Lee, J. K.; Jung, O.-S. J. Mol. Struct., in press.