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Swellable Submicrospheres of Ionic Palladium(II) Complexes Containing Decylmethylbis(m-pyridyl)silane

  • Ryu, Yoon-Kyong (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Kim, Cho-Rong (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Kim, Chi-Won (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Noh, Tae-Hwan (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Jung, Ok-Sang (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
  • Published : 2009.10.20

Abstract

Ionic palladium(II) complex containing a long aliphatic chain, [(tmeda)$PdL]_2(PF_6)_4$ (tmeda = N,N,N',N'-tetramethylethylenediamine; L = decylmethylbis(m-pyridyl)silane) allowed to form a puckered submicrosphere morphology without any template or additive. The puckered spheres reversibly adsorb and desorb dioxane molecules. Coligand and cosolvent effects on the formation of submicrospherical morphology were observed.

Keywords

References

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