Journal of the Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회논문지)

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
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Optical Properties of α-In2S3:Co2+ Single Crystal

α-In2S3:Co2+ 단결정의 광학적 특성에 관한 연구

  • 박광호 (동아인재대학 안경광학과) ;
  • 현승철 (성화대학 안경광학과) ;
  • 정진 (조선대학교 물리학과) ;
  • 오석균 (한국기초과학지원연구원 광주센터)
  • Published : 2008.12.01
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Abstract

The ${\alpha}-In_2S_3:Co^{2+}$ single crystal with a good quality and stabilized property were gained successfully by the CTR(Chemical Transport Reaction)method. XRD analysis showed that the grown single crystals were cubic structure. The optical absorption spectra of ${\alpha}-In_2S_3:Co^{2+}$ single crystal showed impurity absorption peaks due to cobalt impurity. These impurity absorption pesks were assigned to the ligand transition between the split energy levels of $Co^{2+}$ ions sited in $T_d$ symmetry of these semiconductor host lattice.

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References

  1. R. Yoosuf and M. K. Jayaraj, "Optical and photoelectrical properties of ${\beta}-In_{2}S_{3} $thin films prepared by two-stage process", Solar Energy Materials & Solar Cells, Vol. 89, p. 85, 2005 https://doi.org/10.1016/j.solmat.2005.01.004
  2. S. Kosaraju, J. A. Marino, J. A. Harvey, and C. A. Wolden, "Plasma-assisted co- evaporation of $\beta$-indium sulfide thin films", Solar Energy Materials & Solar Cells, Vol. 90, p. 1121, 2006 https://doi.org/10.1016/j.solmat.2005.06.007
  3. W. T. Kim and C. D. Kim, "Optical energy gap of $\beta-In_{2}S_{3}$ thin films grown by spray pyrolysis", J. Appl. Phys., Vol. 60, p. 2631, 1986 https://doi.org/10.1063/1.337137
  4. N. Revathi, P. Prathap, and K. T. Ramakrishna Reddy, "Synthesis and physical behaviour of $In_{2}S_{3}$ films", Applied Surface Science, Vol. 254, p. 5291, 2008 https://doi.org/10.1016/j.apsusc.2008.02.032
  5. N. Kamoun, S. Belgacem, M. Amlouk, R. Bennaceur, J. Bonnet, F. Touhari, M. Nouaoura, and L. Lassabatere, "Structure, surface composition, and electronic properties of $\beta-In_{2}S_{3}$ and $\beta-In_{2-x}Al_{x}S_{3}$", J. App. Phys., Vol. 89, p. 2766, 2001 https://doi.org/10.1063/1.1340003
  6. A. A. El Shazlyy, D. Abd Elhadyyz, H. S. Metwallyy, and M. A. M. Seyamy, "Electrical properties of $\beta-In_{2}S_{3}$ thin films", J. Phys.: Condens. Matter., Vol. 10, p. 5943, 1998 https://doi.org/10.1088/0953-8984/10/26/019
  7. S. H. Choe, T. H. Bang, N. O. Kim, H. G. Kim, C. I. Lee, M. S. Jin, S. K. Oh, and W. T. Kim, "Optical properties of $\beta-In_{2}S_{3}$ and $\beta-In_{2}S_{3}:Co^{2+}$ single crystals", Semicond. Sci. Technol., Vol. 16, p. 98, 2001 https://doi.org/10.1088/0268-1242/16/2/307
  8. G. Caoa, Y. Zhaob, and Z. Wub, "Synthesis and characterization of $In_{2}S_{3}$ nanoparticles", J. Alloys Compd., In press, 2008
  9. S. D. Naik, T. C. Jagadale, S. K. Apte, R. S. Sonawane, M. vol. Kulkarni, S. I. Patil, S. B. Ogale, and B. B. Kale, "Rapid phase-controlled microwave synthesis of nanostructured hierarchical tetragonal and cubic $\beta-In_{2}S_{3}$ dandelion flowers", Chemical Physics Letters, Vol. 452, p. 301, 2008 https://doi.org/10.1016/j.cplett.2007.12.048
  10. Ansell H. G. and Boorman R. S., "Phase relationship in the In-S system", J. Electrochem. Soc., Vol. 118. p. 133, 1971 https://doi.org/10.1149/1.2407925
  11. H. Nakanishi, H. Endo, and T. Irie, "Photoluminescence and photoconduction in the system $(CdIn_{2}S_{4})_{1-x}-(In_{2}S_{3})x$", Jap. J. Appl. Phys., Vol. 20, p. 1481, 1981 https://doi.org/10.1143/JJAP.20.1481
  12. R. Diehl and R. Nitsche, "Vapour growth of three $In_{2}S_{3}$ Modifications by iodine transport, Journal of Crystal Growth", Vol. 28, p. 306, 1975 https://doi.org/10.1016/0022-0248(75)90067-6
  13. G. F. J. Garlick, M. Spring ford, and H. Checinska, "The infra-red emission of indium sesquisulphide", Poc. Phys. Soc., Vol. 82, p. 16, 1963
  14. K. Kambas, J. Spyrldelis, and M. Balkanski, "Far infrared and raman optical study of ${\alpha}$ - and $\beta-In_{2}S_{3}$ Compounds", Phys. Status Solid (b), Vol. 105, p. 291, 1981 https://doi.org/10.1002/pssb.2221050132
  15. R. Nitsche, H. U. Bolsterli, and M. Lichtensteiger, "Crystal growth by chemical transport reactions-I Binary, ternary, and mixed-crystal chalcogenides", J. phys. Chem. Solid, Vol. 21, p. 199, 1961 https://doi.org/10.1016/0022-3697(61)90098-1
  16. A. Likforman, M. Guittard, A. Tomas, and J. Flahaut, "Study of $In_{2}S_{3}$ thin films by diffraction of synchrotron radiation", J. Solid State Chem., Vol. 34, p. 353, 1980 https://doi.org/10.1016/0022-4596(80)90434-X
  17. J. I. Pankov, "Optical Process in Semi- conductors", Dover Pub., New York, p. 36, 1971
  18. S. Sugano, Y. Tanabe, and H. Kamimura, "Multiplets of Transition-metal Ions in Crystals", Academic Press, New York, p. 106, 1970
  19. I. Aksenov, T. Kai, N. Nishikawa, and K. Sato, "Optical absorption of $Co^{2+}}$ in $CuAlS_{2}$", Jap. J. Appl. Phys., Vol. 32, p. L516, 1993 https://doi.org/10.1143/JJAP.32.L516
  20. Y.-L. Lee and W.-T. Kim, "Structural and optical properties of $Zn_{1-x}Cd_{x}Ga_{2}Se_{4} and Zn_{1-x}Cd_{x}Ga_{2}Se_{4}:Co^{2+}$ single crystals", Phys. Rev., Vol. B50, p. 10672, 1994.