Manufacture and Properties of Inorganic Chemical Treated Wood by Introducing of Fluorides

  • Received : 2008.02.11
  • Accepted : 2008.03.21
  • Published : 2008.03.25

Abstract

Inorganic chemical treated wood was prepared by impregnation of calcium or magnesium chloride ($CaCl_2$ or $MgCl_2$) solution and immersion in saturated solution of ammonium fluoride ($NH_4F$) as a reactant in order to make an introduction of a refractory fluorides with fungicidal and insecticidal effects in wood. The weight percent gains (WPGs) were increased with increase in concentration of calcium chloride or magnesium chloride solution, and were higher in treatment with calcium chloride than with magnesium chloride. Inorganic substances were produced mainly in the lumina of tracheides. These substances were proved to be the calcium fluoride or magnesium fluoride by the energy dispersive X-ray analyzer in conjunction with a scanning electron microscope (SEM-EDX). The treated wood showed good decay resistance because the weight losses were hardly occurred by the test fungi such as Tyromyces palustris and Trametes versicolor. The fire resistance effect was superior to the treated wood compared with that of the untreated wood.

Keywords

References

  1. Eaton, R. A. and M. D. C. Hale. 1993. Wood: Decay, pests and protection. pp. 358. Chapman & Hall. London.
  2. Furuno, T., T. Uehara, and S. Jodai. 1991. Combinations of wood and silicate I: Impregnation by water glass and applications of aluminum sulfate and calcium chloride as reactants. Mokuzai Gakkaishi 37(5): 462-472.
  3. Japan wood preserver's association. 1982. Wood preservation. pp. 126-127. Bunkyou Syuppan. Osaka.
  4. Lee, J. S. and S. J. Kim. 2008. Manufacture and properties of gypsum-wood. Journal of the Korea Furniture Society 19(1): 83-90.
  5. Moon, S. M. 1995. Chemical product dictionary. pp. 327. Korea dictionary research publishing. Seoul.
  6. Saka, S., M. Sasaki, and M. Tanahashi. 1992. Wood-inorganic composites prepared by sol-gel processing I: Wood-inorganic composites with porous structure. Mokuzai Gakkaishi 38(11): 1043-1049.
  7. Yoon, S. M. and J. S. Lee. 2001. Formation and preservative effectiveness of inorganic substances in wood treated with potassium carbonate and calcium chloride. Mokchae Konghak 29(2): 126-132.