Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
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Catalytic Performance of Ionic Liquids for the Cycloaddition of Carbon Dioxide and Butyl Glycidyl Ether

부틸글리시딜에테르와 이산화탄소의 부가반응에 대한 이온성 액체의 촉매 성능 고찰

  • Park, Dae-Won (Department of Chemical Engineering, Pusan National University) ;
  • Ju, Hye-Young (Department of Chemical Engineering, Pusan National University) ;
  • 박대원 (부산대학교 공과대학 응용화학공학부) ;
  • 주혜영 (부산대학교 공과대학 응용화학공학부) ;
  • 이미경 (부산대학교 공과대학 응용화학공학부)
  • Published : 2008.12.31
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Abstract

The synthesis of cyclic carbonate from butyl glycidyl ether (BGE) and carbon dioxide was performed in the presence of three different types of ionic liquid : quarternary ammonium salt, alkyl pyridinium salt, and alkylimidazolium salt. Ionic liquids of different alkyl groups ($C_3$, $C_4$, $C_6$ and $C_8$) and anions ($Cl^-$, $Br^-$ and $I^-$) were used for the reaction which was carried out in a batch autoclave reactor at $60{\sim}120^{\circ}C$. The catalytic activity was increased with increasing alkyl chain length in the order of $C_3$ < $C_4$ < $C_6$. But the ionic liquid with longer alkyl chain length ($C_8$) decreased the conversion of BGE because it is too bulky to form an intermediate with BGE. For the counter anion of the ionic liquid catalysts, the BGE conversion decreased in the order $Cl^-$ > $Br^-$ > $I^-$.

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References

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