Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Formation of Complex XeHCl+ in the Xe++ HCl Collision

  • Ree, Jong-Baik (Department of Chemistry Education, Chonnam National University) ;
  • Kim, Yoo-Hang (Department of Chemistry and Center for Chemical Dynamics) ;
  • Shin, Hyung-Kyu (Department of Chemistry, University of Nevada)
  • Published : 2008.04.20
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Abstract

The formation of complex $XeHCl^+$ in the collision-induced reaction of $Xe^+$ with HCl has been studied by use of classical dynamics procedures using the London-Eyring-Polanyi-Sato empirical potential energy surfaces. A small fraction of trajectories on the $Xe^+$ + HCl and Xe + $HCl^+$ surfaces lead to the formation of complex $XeHCl^+$ with life-times of 1-2 ps which is long enough to survive many rotations before redissociating back to the reactant state. The formation of complex $XeHCl^+$ occurs mainly from collision angle of $\Theta$ = ${45^{\circ}}$.

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