Acid Corrosion Resistance and Durability of Alkali-Activated Fly Ash Cement-Concrete

알칼리활성 플라이 애쉬 시멘트-콘크리트의 산저항성 및 내구성

  • Kang, Hwa-Young (Department of Civil and Environment, Hanyeong College) ;
  • Park, Sang-Sook (Division of Civil and Environmental Engineering, Sunchon National University) ;
  • Han, Sang-Ho (Division of Civil and Environmental Engineering, Sunchon National University)
  • 강화영 (한영대학 토목환경과) ;
  • 박상숙 (순천대학교 토목.환경공학부) ;
  • 한상호 (순천대학교 토목.환경공학부)
  • Published : 2008.01.31

Abstract

A new cementitious material has been developed, called alkali-activated fly ash cement(AAFC), which is used to produce AAFC-concrete for construction. The effect of acid attack, sodium chloride solution, carbonation, freeze-thaw cycling, and SEM, XRD analysis of the AAFC-concrete prepared using alkali-activated fly ash cement and OPC-concrete were experimentally investigated. It was found that the acid resistance of AAFC-concrete(35 MPa) prepared from alkali-activated fly ash at 85$^{\circ}C$ for 24 hrs is far better than OPC-concrete(35 MPa). Also, the AAFC-concrete(35 MPa) had a similar resistance of OPC-concrete(35 MPa) to attack, such as sodium chloride solution, carbonation and freeze-thaw cycling.

알칼리활성 플라이 애쉬 시멘트(AAFC)라 불리는 새로운 시멘트 물질을 이용하여 AAFC-콘크리트를 제조하였다. 알칼리활성 플라이 애쉬 시멘트를 사용하여 제조한 AAFC-콘크리트와 OPC-콘크리트에 대하여 산 침투, 염분, 탄산화, 동결 융해에 대한 영향과 SEM, XRD 분석을 수행하였다. 플라이 애쉬를 85$^{\circ}C$에서 24시간 동안 알칼리 활성화하여 제조한 AAFC-콘크리트(35 MPa)의 산 저항성은 OPC-콘크리트(35 MPa)보다 훨씬 뛰어난 것으로 나타났다. 또한 AAFC-콘크리트(35 MPa)는 염분용액, 탄산화 그리고 동결-융해와 같은 공격에 OPC-콘크리트(35 MPa)와 비슷한 저항성을 가지고 있는 것으로 나타났다.

Keywords

References

  1. 한국전력공사, "1999년 석탄회 발생 및 재활용실적 보고서,"(2000)
  2. Cochrane, J. W. and Boyd, T. J., "Benification of Fly Ash by Carbon Burnout," in Proc. 10th Ash Use Symp., Jan. (1993)
  3. 백민수, 정상진, "플라이 애쉬를 다량 치환한 콘크리트의 초기특성에 관한 실험적 연구," 대한건축학회논문집 구조계, 18(11), 91-97(2002)
  4. Hossein, R. and William, B., "Alkali Ash Material: A Novel Fly Ash-Based Cement," Environ. Sci. Technol., 37(15), 3454-3457(2003) https://doi.org/10.1021/es026317b
  5. Arjunan, P., Silsbee, M. R., and Roy, D. M., "Chemical Activation of Low Calcium Fly Ash: Part I: identification of the Most Appropriate Activators and Their Dosage," Proceedings of the Intl. Ash Utilization Symposium, Kentucky(2001)
  6. Puertas, F. and Fernandez-Jimenez, A., "Mineralogical and Microstructural Characterisation of Alkali-activated Fly Ash/ Slag Pastes," Cem. Concr. Res., 25, 287-292(2003) https://doi.org/10.1016/S0958-9465(02)00059-8
  7. Williams, P. J., Biernacki, J. J., Walker, L. R., Meyer, H. M., Rawn, C. J., and Bai, J., "Microanalysis of Alkaliactivated Fly Ash-CH Pastes," Cem. Concr. Res., 32, 963-972(2002) https://doi.org/10.1016/S0008-8846(02)00734-2
  8. 박상숙, 강화영, 한상호, 임요섭, 김동국, "알칼리-활성 플 라이 애쉬 페이스트의 압축강도에 대합 배합조건 및 물유 리 모듈의 영향," 한국폐기물학회지, 23(7), 591-599(2006)
  9. 한상호, 박상숙, 강화영, "플라이 애쉬를 활용한 알칼리 활성시멘트 콘크리트의 압축강도와 최적혼합비," 한국구조물진단학회지, 11(4), 152-158(2007)
  10. Synder, R., Esfandi, E., Surapaneni, S., "Control concrete sewer corrosion via the crown spray process," Water Environ Res., 68, 338-347(1996) https://doi.org/10.2175/106143096X127785
  11. Mehta, P. K., "Studies on chemical resistance of low water/cement ratio concrete," Cem. Concr. Res., 15, 969- 978(1985) https://doi.org/10.1016/0008-8846(85)90087-0
  12. Roy, D.M., Arjunan, P., Silsbee, M.R., "Effect of silica fume, metakaolin, and low-calcium fly ash on chemical resistance of concrete," Cem. Concr. Res., 31, 1809-1813(2001) https://doi.org/10.1016/S0008-8846(01)00548-8
  13. Vesa Penttala and Fahim Al-Neshawy, "Stress and strain stste of concrete during freezing and thawing cycles," Cem. Concr. Res., 32, 1407-1420(2002) https://doi.org/10.1016/S0008-8846(02)00785-8
  14. Li, D., Chen, Y., Shen, J., Su, J. and Wu, X., "The influence of alkalinity on activation and microstructure of fly ash," Cem. Concr. Res., 30, 881-886(2000) https://doi.org/10.1016/S0008-8846(00)00252-0
  15. Palomo, A., Alonso, S., Fernandez-Jimenez, A., Sobrados, I., sanz, J., "Alkaline activation of fly ashes. A 29Si NMR study of the reaction products," J. Am. Ceram. Soc., 87(6), 1141-1145(2004) https://doi.org/10.1111/j.1551-2916.2004.01141.x
  16. Zhaohui Xie and Yunping Xi, "Hardening mechanism of an alkaline-activated class F fly ash," Cem. Concr. Res., 31, 1245-1249(2001) https://doi.org/10.1016/S0008-8846(01)00571-3