Influence of Hwangto on the Mechanical Properties of Wood Flour Reinforced High Density Polyethylene (HDPE) Composites

  • Lee, Sun-Young (Laboratory of Functional Wooden Materials, Department of Forest Products, Korea Forest Research Institute) ;
  • Doh, Geum-Hyun (Laboratory of Functional Wooden Materials, Department of Forest Products, Korea Forest Research Institute) ;
  • Kang, In-Aeh (Laboratory of Functional Wooden Materials, Department of Forest Products, Korea Forest Research Institute) ;
  • Wu, Qinglin (School of Renewable Natural Resources, Louisiana State University Agricultural Center)
  • Received : 2006.06.09
  • Accepted : 2006.07.07
  • Published : 2007.03.25

Abstract

The mechanical properties of wood flour, Hwangto (325 and 1,400 mesh per 25,4 mm) and coupling agent-reinforced HDPE composites were investigated in this study. Hwangto and maleated polyethylene (MAPE) were used as an inorganic filler and a coupling agent, respectively. The addition of Hwangto and MAPE to virgin HDPE also increased the Young's modulus in the smaller degree. The addition of wood flour and Hwangto to virgin HDPE increased the tensile strength, due to the high uniform dispersion of HDPE by high surface area of Hwangto in HDPE and wood flour. MAPE also significantly increased the tensile strength. When wood flour was added, there was no notable difference on the tensile properties, in terms of Hwangto particle size. Hwangto also improved the flexural modulus and strength of reinforced HDPE composites. With different particle sizes of Hwangto, there was no considerable difference in flexural modulus and strength of reinforced HDPE composites. The addition of Hwangto showed slightly lower impact strength than that of wood flour. However, the particle size of Hwangto showed no significant effect on the impact strength of reinforced composites. In conclusion, reinforced HDPE composites with organic and inorganic fillers provide highly improved mechanical properties over virgin HDPE.

Keywords

References

  1. Bates, R. L. and J. A. Jackson. 1987. Glossary of Geology (3rd Ed.). Amer. Geol. Inst, Alexandria. pp. 387
  2. Cho, H. G., D. Y. Yang, and Y. H. Kim. 2003. The copper adsorption onto 'Hwangto' in the Okjong Area, Hadong. J. Miner. Soc. Korea. 16 (4): 321-331
  3. Choi, S. W., H. Y. Choi, H. Z. Hwang, M. H. Kim, and M. H. Kim. 2000. An experimental stndy on the basic properties of concrete with Hwangtoh admixtnre. Proceeding of Architectural Institnte of Korea. 20(2): 419-422
  4. Chorover, J. and G. Sposito. 1995. Surface charge characteristics of kaolinite tropical soils. Geochemica et Cosmochimica Acta. 59: 875-884 https://doi.org/10.1016/0016-7037(94)00357-2
  5. Clemons, C. 2002. Wood-plastic composites in the United States: The interfacing of two industries. Forest Products J. 52(6): 1-8
  6. Jana, S. C. and A. Prieto. 2002. On the development of natural fiber composites of high temperature thermoplastic polymers. J. Applied Polymer Science. 86: 2159-2167 https://doi.org/10.1002/app.11073
  7. Keller, A. 2003. Compounding and mechanical properties of biodegradable hemp fibre composites. Composites Science and Technology. 63: 1307-1316 https://doi.org/10.1016/S0266-3538(03)00102-7
  8. Leaversuch, R. D. 2000. Wood-fiber composites build promising role in extrusion. Modern Plastics. Dec. pp. 56-59
  9. Lee, S. Y., H. S. Yang, H. J. Kim, C. S. Jeong, B. S. Lim, and J. N. Kim. 2004. Creep behavior and manufacturing parameters of wood flour filled propylene composites. Composite Structures. 65: 459-469 https://doi.org/10.1016/j.compstruct.2003.12.007
  10. Lopez-Manchado, M. A. and M. Arroyo. 2000. Thermal and dynamic properties of polypropylene and short organic fiber composites. Polymer. 41: 7761-7767 https://doi.org/10.1016/S0032-3861(00)00152-X
  11. Lu, J. Z., Q. Wu, and H. S. McNabb Jr. 2000. Chemical coupling in wood fiber and polymer composites: a review of coupling agents and treatments. Wood Fiber Sci. 32(1): 88-104
  12. Lu, J. Z., Q. Wu., and I. Negluescue. 2002. Influence of maleation on polymer adsorption and fixation, wood surface wettability, and interfacial bonding strength in wood-PVC composites. Wood Fiber Sci. 34(3): 434-459
  13. Maplestone, P. 2001. It is one hot market for profile extruders. Modern Plastics. Aug. 49-52
  14. Mishra, S., A. K. Mohanty, L. T. Drzal, M. Misra, S. Parija, S. K. Nayak, and S. S. Tripathy. 2003. Studies on mechanical performance of biofibre/glass reinforced polymer hybrid composites. Composites Science and Technology. 63: 1377-1385 https://doi.org/10.1016/S0266-3538(03)00084-8
  15. Nair, K. C., S. Thomas, and G. Groeninckx. 2001. Thermal and dynamic mechanicalanalysis of polystyrene composites reinforced with short fibres. Composites Science and Technology. 61: 2519-2529 https://doi.org/10.1016/S0266-3538(01)00170-1
  16. Pritchard, G. 1998. Quick reference guide. Page 12 in G. Pritchard, ed. Plastics additives: An A-Z reference, Chapman and Hall, New York, NY
  17. Ryu, D. W. and C. H. Seo. 2000. An experimental study on the manufacturing and properties of cement composites with ocher. Proceeding of Architectural Institute of Korea. 20(2): 391-394
  18. Stark, N. and R. E. Rowlands. 2003. Effects of wood fiber characteristics on mechanical properties of wood/polypropylene composites. Wood Fiber Sci. 35(2): 167-174
  19. Yang, K. H., S. Y. Kim, and J. G. Song. 2006. The mechanical characteristics of concrete mixed with activated Hwangtoh and specialty cellulose fiber. Proceeding of Architectural Institute of Korea. 22(1): 111-118