Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Endo- and Exo-Coordinated Mercury(II) Complexes of O3S2 Macrocycles: Effect of Dibenzo-Substituents on Coordination Mode

  • Lee, Ji-Eun (Department of Chemistry (BK21) and Research Institute of Natural Science, Gyeongsang National University) ;
  • Kim, Hyun-Jee (Department of Chemistry (BK21) and Research Institute of Natural Science, Gyeongsang National University) ;
  • Lee, So-Young (Department of Chemistry (BK21) and Research Institute of Natural Science, Gyeongsang National University) ;
  • Lee, Jai-Young (Department of Chemistry (BK21) and Research Institute of Natural Science, Gyeongsang National University) ;
  • Jin, Yong-Nu (Department of Chemistry (BK21) and Research Institute of Natural Science, Gyeongsang National University) ;
  • Lee, Shim-Sung (Department of Chemistry (BK21) and Research Institute of Natural Science, Gyeongsang National University)
  • Published : 2007.11.20
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Abstract

The reactions of mercury(II) chloride with O3S2-donor macrocyclic ligands with (L1) and without (L2) dibenzosubunit afforded respective exo- (1) and endo-coordinated (2) complexes depending on the ring rigidity of the ligands. From the X-ray crystal structures and comparative NMR studies for the complexes 1 and 2, it is confirmed that the resulting species with different coordination modes exist not only in solid state but also in solution state.

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