DOI QR코드

DOI QR Code

Preparation of nanocrystalline CuO powders by hydrazine method and their gas sensing characteristics

Hydrazine 법에 의한 CuO 미분말의 합성 및 가스 감응성 평가

  • Kim, Sun-Jung (Department of Materials Science & Engineering, Korea University) ;
  • Lee, Jong-Heun (Department of Materials Science & Engineering, Korea University)
  • Published : 2007.01.31

Abstract

CuO is an important transition metal oxide with many practical applications such as catalysts, p-type semiconductor, solar cells, magnetic storage media and cathode materials. In this contribution, nanocrystalline CuO powders were prepared by solution reduction method using copper chloride ($CuCl_{2}{\cdot}2H_{2}O$), hydrazine ($N_{2}H_{4}$) and NaOH and subsequent heat treatment. The gas sensor using nanocrystalline CuO powders showed high sensitivities to acetone and ethanol.

Keywords

References

  1. D. D. Vuong, G. Sakai, K. Shimanoe, and N. Yamazoe, 'Preparation of grain size-controlled tin oxide sols by hydrothelmal treatment for thin film sensor application', Sens. & Actuators B, vol. 103, pp. 386-391, 2004 https://doi.org/10.1016/j.snb.2004.04.122
  2. J. F. Chang, H. H. KuO, I. C. Leu, and M. H. Hon, 'The effects ofthickness and operation temperature on ZnO:Al thin film CO gas sensor', Sens. & Actuators B, vol. 84 pp. 258-264, 2004
  3. C. Cantalini, W. Wlodarski, H. T. Sun, M. Z. Atashbar, M. Passacantando, and S. Santucci, '$NO_2$ response of $In_2O_3$ thin film gas sensors prepared by sol-gel and vacuum thermal evaporation techniques', Sens. & Actuators B, vol. 65, pp. 101-104, 2000 https://doi.org/10.1016/S0925-4005(99)00439-6
  4. J. S. Han, T. Bredow, D. E. Davey, A. B. Yu, and D. E. Mulcahy, 'The effect of Al addition on the gas sensing properties of $Fe_2O_3$-based sensors', Sens. & Actuators B, vol. 75, pp. 18-23, 2001 https://doi.org/10.1016/S0925-4005(00)00688-2
  5. Y. G. Choi, G. Sakai, K. Shimanoe, and N. Yamazoe, 'Wet process-based fabrication of $WO_3$ thin film for $NO_2$ detection', Sens. & Actuators B, vol. 101, pp. 107-111, 2004 https://doi.org/10.1016/j.snb.2004.02.031
  6. M. N. Rumyantseva, M. Labeau, J. P. Senateur, G. Delabouglise, M. N. Boulova, and A. M. Gaskov, 'Influence of copper on sensor properties of tin dioxide films in $H_2S$', Mater. Sci. & Eng. B, vol. 41, pp. 228-234, 1996 https://doi.org/10.1016/S0921-5107(96)01601-7
  7. J. D. Choi and G. M. Choi, 'Electrical and CO gas sensing properties of layered ZnO-CuO sensor', Sens. & Actuators B, vol. 69, pp. 120-126, 2000 https://doi.org/10.1016/S0925-4005(00)00519-0
  8. S. Aygun and D. Cann, 'Hydrogen sensitivity of doped CuO/ZnO heterocontact sensors', Sens. & Actuators B, vol. 106, pp. 837-842, 2005 https://doi.org/10.1016/j.snb.2004.10.004
  9. J. Zhang, J. Liu, Q. Peng, X. Wang, and Y. Li, 'Nearly monodisperse $CU_2O$ and CuO nanospheres: Preparation and applications for sensitive gas sensors', Chem. Mater., vol. 18, pp. 867-871, 2006 https://doi.org/10.1021/cm052256f
  10. 김강민, 김기원, 조평석, 이종흔, 'Hydrazine 법에 의한 SnO, $SnO_2$ 미분말의 합성', 센서학회지, 제14권, 제5호, pp. 297-301, 2005 https://doi.org/10.5369/JSST.2005.14.5.297
  11. K. W. Kim, P. S. Cho, S. J. Kim, J. H. Lee, C. Y. Kang, J. S. Kim, and S. J. Yoon, 'The selective detection of $C_2H_5OH$ using $SnO_2$-ZnO thin film gas sensors prepared by combinatorial solution deposition', Sens. & Actuators B, In press
  12. T. Tsuboi, K. Ishii, and S. Tamura, 'Thermal oxidation of acetone behind reflected shock wave', in Proceedings of the 17th International Colloquium on the Dynamics of Explosions and Reactive Systems, Heidelberg, Germany, July 25-30, 1999
  13. G. Mangamma, V. Jayaraman, T. Gnanasekaran, and G. Periaswami, 'Effects of silica additions on $H_2S$ sensing properties of CUO-$SnO_2$ sensors', Sens. & Actuators B, vol. 53, pp. 133-139, 1998 https://doi.org/10.1016/S0925-4005(99)00006-4

Cited by

  1. Preparation of Manganese Oxide Porous Nanostructures using Amino-acid and its Selective C3H8Sensing Properties vol.20, pp.1, 2011, https://doi.org/10.5369/JSST.2011.20.1.64