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연료전지용 천연가스 자열개질기의 기초특성 연구

Study on Basic Characteristics of Natural Gas Autothermal Reformer for Fuel Cell Applications

  • 임성광 (한국과학기술원 기계공학과) ;
  • 남석우 (한국과학기술원 환경공정연구부) ;
  • 배중면 (한국과학기술원 기계공학과)
  • 발행 : 2006.09.01

초록

Hydrogen production using current fueling facilities is essential for near-term applications of fuel cells. A preliminary process for developing a natural gas autothermal reforming (ATR) reactor for fuel cells is presented in this paper. A experimental reactor for methane ATR was constructed and used for characterization of Jin reactor. Temperature profiles of the reactor were observed, and reformed gas compositions were analyzed to evaluate efficiency, conversion and reaction heat with varying amounts of $O_2/CH_4$ at selected furnace temperature and $H_2O/CH_4$. The amount of $O_2/CH_4$ showed strong offsets on reactor temperature, efficiency and conversion indicating that $O_2/CH_4$ is a crucial operation condition. Operation conditions which result in thermal neutrality of ATR reactor system were determined for two cases of an ATR system based on the estimation of enthalpy difference between reactants of assumed inlet temperatures and the products from experimental results. The determined conditions for thermally neutral operations could be used for guidelines to design reformers and for determining the operation parameters of a self sustaining ATR reactor.

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참고문헌

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