한국섬유공학회지 (Textile Science and Engineering)

  • 제43권3호
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  • Pages.114-120
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  • 2006
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  • 1225-1089(pISSN)
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  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지

폴리벤즈옥사졸 전구체를 이용한 나노섬유의 제조

Preparation of Nanofibers Using Precursor Polymers to Polybenzoxazoles

  • 백두현 (충남대학교 공과대학 유기소재 섬유시스템) ;
  • 임수진 (충남대학교 공과대학 유기소재 섬유시스템)
  • Baik Doo-Hyun (Department of Organic Materials and Textile System, Chungnam National University) ;
  • Im Su-Jin (Department of Organic Materials and Textile System, Chungnam National University)
  • 발행 : 2006.06.01
⟨ 이전 논문 다음 논문 ⟩

초록

Polyhydroxyamide, a precursor polymer to polybenzoxazole, was synthesized by low temperature polymerization of dihydroxybenzidine and isophthaloyl chloride. The polyhydroxyamide solution was electro spun under appropriate concentration, viscosity, electrical conductivity, voltage and tip collector distance. Electrospun polyhydroxyamide fibers were heated at the elevated temperature and converted to polybenzoxazole fibers. In this study we investigated the effects of the electrospinning factors, such as solution viscosity, concentration, and electrical conductivity on the fiber formation of polyhydroxyamide during electro spinning. The electrospun polyhydroxyamide nanofibers showed broader DSC endothermic peak as compared to film or powder samples, which was thought to be due to the large sur-face area of nanofiber web.

키워드

참고문헌

  1. D. H. Baik, H. Y. Kim, and S. W. Kantor, 'Synthesis and Cyclization of Aromatic Polyhydroxyamides Containing Trifluoromethyl Groups', Fibers and Polymers, 2002, 3(3), 91-96 https://doi.org/10.1007/BF02892623
  2. C. Huang, S. Wang, H. Zhang, T. Li, S. Chen, C. Lai, and H. Hou, 'High Strength Electrospun Polymer Nanofibers Made from BPDA-PDA Polyimide', Eur Polym J, 2006, 42, 1099-1104 https://doi.org/10.1016/j.eurpolymj.2005.11.005
  3. C. K. Lee, S. I. Kim, and S. J. Kim, 'The Influence of Added Ionic Salt on Nanofiber Uniformity for Electrospinning of Electrolyte Polymer', Synthetic Metals, 2005, 154, 209-212 https://doi.org/10.1016/j.synthmet.2005.07.053
  4. V. J. Nagpal, R. M. Davis, Q. Liu, J. Facinelli, and J. S. Riffle, 'A Dynamic Light Scattering Study of Micelle Formation in Solutions of Poly(2-ethyl-2-oxazolinedimethylsiloxane) in Water-2-propanol Mixtures', Langmuir, 1994, 10, 4434-4439 https://doi.org/10.1021/la00024a010
  5. P. Gupta, C. Elkins, T. E. Long, and G. L. Wilkes, 'Electrospinning of Linear Homopolymers of Poly(methyl methacrylate): Exploring Relationships between Fiber Formation, Viscosity, Molecular Weight and Concentration in a Good Solvent', Polymer, 2005, 46, 4799-4810 https://doi.org/10.1016/j.polymer.2005.04.021
  6. W. E. Krause, E. G. Bellomo, and R. H. Colby, 'Rheology of Sodium Hyaluronate Under Physiological Conditions', Biomacromolecules, 2001, 2(1), 65-69 https://doi.org/10.1021/bm0055798
  7. Y. M. Shin, M. M. Hohman, M. P. Brenner, and G. C. Rutledge, 'Experimental Characterization of Electrospinning: the Electrically Forced Jet and Instabilities', Polymer, 2001, 42, 9955-9967 https://doi.org/10.1016/S0032-3861(01)00540-7
  8. C. Lu, P. Chen, J. Li, and Y. Zhang, 'Computer Simulation of Electrospinning. Part I. Effect of Solvent in Electrospinning', Polymer, 2006, 47, 915-921 https://doi.org/10.1016/j.polymer.2005.11.090