환경영향평가 (Journal of Environmental Impact Assessment)

한국환경영향평가학회 (Korean Society of Environmental Impact Assessment)
권호 표지

기기중성자방사화분석을 이용한 대전 3, 4 공단지역의 호흡성입자의 특성

Characteristics of Respirable Particulate Matter from the Third and Fourth Industrial Complex Area of Daejeon City Using Instrumental Neutron Activation Analysis

  • Lim, Joung-Myoung (Department of Environmental Engineering, Chungnam National University) ;
  • Lee, Jin-Hong (Department of Environmental Engineering, Chungnam National University)
  • 투고 : 2006.09.18
  • 심사 : 2006.11.14
  • 발행 : 2006.12.30
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Instrumental neutron activation analysis was used to measure the concentrations of 27 elements associated with respirable particulate matter (PM10) that were collected from the Third and Fourth Industrial Complex Area of Daejeon City. The distribution patterns of elements were clearly distinguished with their concentrations varying across more than four orders of magnitude. The mean for Al were recorded to be the highest value of 1,527 $ng/m^3$, while that for In showed the lowest value of 0.1 $ng/m^3$. If compared in terms of enrichment factors, it was found that certain elements (e.g., As, Br, Cl, Cr, I, In, Sb, Se, and Zn) are enriched in PM10 samples of the study site. The results of factor analysis indicated six factors with statistical significance, which may exert dominant controls on regulating the elemental concentration levels in the study area.

키워드

참고문헌

  1. 경기개발연구원, 2003, 경기도지역 대기오염의 사회적 비용추정 및 적정 수준 달성 방안, 경기개발연구원
  2. 김병화, 김동술, 2000, 수원지역 대기 중 PM2.5와 PM10의 환경거동에 관한 연구, 한국대기환경학회지, 16(2), 89-101
  3. 박진수, 김신도, 2005, 서울과 인천지역 PM10과 PM2.5 중 2차생성 탄소성분 추정, 한국대기환경학회지, 21(1), 131-140
  4. 이진흥, 장미숙, 임종명, 2002 , 다양한 통계기법을 이용한 대전 1, 2 공단지역의 미량금속원소 의 특성연구, 한국대기환경학회지, 18(2), 95-112
  5. 조용성, 이홍석, 김윤신, 이종태, 박진수, 2003, 서울 성동구 지역 미세먼지의 화학적 조성에 관한 연구, 한국환경과학회지, 12(6), 665-676
  6. 한진석, 문광주, 공부주, 류성윤, 김영준, 2004, 인자분석을 통한 대기 입자상 물질의 입경별 발생원 추정 -Drum impactor 를 이용한 2002 년 5월 제주도 고산지역 측정을 중심으 로, 한국대기환경학회지, 20(5), 685-695
  7. 황인조, 김동술, 2003, PMF 모델을 이용한 대기 중 PM-10 오염원의 확인, 한국대기환경학회지 , 19(6), 701-717
  8. Braga, C F., Teixeira, E. C , Meira, L., Wiegand, F. , Yoneama, M. L., and Dias, J. F. , 2005, Elemental composition of PM10 and PM2.5 in urban environment in South Brazil, Atmospheric Eηνironment, 39, 1801-1815 https://doi.org/10.1016/j.atmosenv.2004.12.004
  9. Chueinta, W., Hopke, P. K., and Paatero, P. , 2000, Investigation of source of atmospheric aerosol at urban and suburban residential areas in Thailand by positive matrix factorization, Atmospheric Envimηment, 34, 3319-3329 https://doi.org/10.1016/S1352-2310(99)00433-1
  10. Cohen, D. D. , Gulson, B. L., Davis, J. M. , Stelcer, E. , Garton, D., Hawas, 0., and Taylor, A., 2005, Fine-particle Mn and other metals linked to the introduction of MMT into gasoline in Sydney, Australia: Results of a natural experiment, Atmospheric Environment, 39, 6885-6896 https://doi.org/10.1016/j.atmosenv.2005.08.006
  11. Dockery, D. W. and Pope III, C. A. , 1994, Acute respiratory effects of particulate air pollution, Annual Reviezν of Public Health, 15, 107-132 https://doi.org/10.1146/annurev.pu.15.050194.000543
  12. Eisenreich, S. J., Metzer, N. A., and Urban, N R., 1986, Response of atmospheric lead to decreased use of lead in gasoline, Environ. Sci. and Technol , 20, 171-174 https://doi.org/10.1021/es00144a010
  13. Galbreath, K. C, Toman, D. I., Zygarlicke, C J., Huggins, F. E. , Huffman, G. P. , and Wong, J. L., 2000, Nickel speciation of residual oil fly ash and ambient particulate matter using X-ray absorption spectroscopy, Journal of the Air and Waste Management Association,50, 1876-1886 https://doi.org/10.1080/10473289.2000.10464230
  14. Han,J. S., Moon, K. J., Lee, S. J., Kim, J. E., and Kim, Y. J., 2005, Size distribution characteristics of particulate mass and ion components at Gosan, J Kosae, 21(1), 1-11
  15. Hopke, P. K., Gladney, E. S., Gordon, G. E., Zoller, W. H., and Jones, A. G. , 1976, The use of multivariate analysis to identify sources of selected elements in the Boston urban aerosol, Atmospheric Environment, 10, 1015-1025 https://doi.org/10.1016/0004-6981(76)90211-0
  16. Hopke, P. K., 1985, Receptor modeling in environmental chemistry, P. 319, John Wiley & Sons, New York, NY
  17. Huang, X. C , Ilhan, O., and Namik, A. K., 1994, Emissions of trace elements from motor vehicles: Potential marker elements and source composition profile, Atmospheric Environment, 28, 1385-1391 https://doi.org/10.1016/1352-2310(94)90201-1
  18. Juichang, R. Freedman, B., Coles, C , Zwicker, B., Holzbecker, J., and Chatt, A., 1995, Vanadium contamination of lichens and tree foliage in the vicinity of 3 oil-flfed power plants in eastern Canada ,Journal of the Air and Waste Management Association, 45, 461--464 https://doi.org/10.1080/10473289.1995.10467376
  19. Kim, B. M. and Henry, R. C , 2000, Application of SAFER model to the Los Angeles PM10 data, Atmospheric Environment, 34, 1747-1759 https://doi.org/10.1016/S1352-2310(99)00365-9
  20. Landsberger, S. , 1999, Trace element determination of airborne particles by Neutron Activation Analysis, in Elemental analysis of airborne particles, p. 323, Gordon and Breach, Malaysia
  21. Lim, J. M., Lee , J. H., and Chung, Y. S., 2005, The distribution characteristics of trace elements in airbome particulates from an urban industrial complex area of Korea using instrumental neutron activation analysis, Nuclear Engineering and Technology, 37(5), 503-510
  22. Lippmann, M. , 1998, The 1997 USEPA standards for particulate matter and ozone. In: Hester, RE., Harrison, RM. (Eds.), Issues in Environmental Science and Technology, Vol. 10. Royal Society of Chemistry, UK, pp. 75-99
  23. Monaci, F. and Bagagli, R, 1987, Barium and other trace metals as indicators of vehicle emissions, Water, Air, and Soil Pollution, 100, 89-98 https://doi.org/10.1023/A:1018318427017
  24. Natusch, D. F. S., Wallace, J. R, and Evans C. A. Jr., 1974, Toxic trace elements: Preferential concentration in respirable particles, Science, 183, 202-204 https://doi.org/10.1126/science.183.4121.202
  25. Ondov J. M, Zoller, W. H. , and Gordon, G E. , 1982, Trace element emission on aerosols from motor vehicles, Environ. Sci. Technol. , 16, 318-328
  26. ORD, 1999, Compendium of methods for the determination of inorganic compounds in ambient air, Center for Environmental Research Information, USEPA, Office of Research and Development
  27. Ostro, B. D. , Hurley, S. , and Lipsett, M. J., 1999, Air pollution and daily mortality in the Coachella Valley, California: A study of PM10 dominated by coarse particles, EnvironmentaI Research, A81, 231-238
  28. Pirrone, N. and Keeler, G. J., 1996, A preliminary assessment of the urban pollution in the Great Lakes region, The Science of the Total Environment, 189/190, 91-98 https://doi.org/10.1016/0048-9697(96)05195-9
  29. Polissar, A. V., Hopke, P. K., and Poirot, R L., 2001, Atmospheric aerosol over Vermont: Chemical composition and sources, Environ. Sci. Technol. , 35, 4604-4621 https://doi.org/10.1021/es0105865
  30. Roscoe, B. A., Hopke, P. K., Dattner, S. L., and Jenks, M. , 1982, The Use of Principal component factor analysis to interpret particulate compositional sata sets, J. of the Air Pollution Control Association, 32, 637-642 https://doi.org/10.1080/00022470.1982.10465439
  31. Salma, I. and Zemplen-Papp, E. , 1999, Instrumental neutron activation analysis for studying size fractionated aerosols, Nucl. Instrum. Meth. in Phys. Reser. , A435, 462-472
  32. Thomas , R, 2002, A beginner's guide to ICP-MS; Part IX-mass analyzer: collision/reaction cell technology, Spectroscopy, 17(2), 42-48
  33. Vallius, M. , Janssen, N. A. H. , Heirich, J., Hoek, G. , Ruuskanen, J., Cyrys, J., Grieken, R. V., Hartog, J. J., Kreyling, W. G., and Pekkanen, J., 2005, Sources and elemental composition of ambient PM2.5 in three European cities, Science of the Total Environment, 337, 147-162 https://doi.org/10.1016/j.scitotenv.2004.06.018
  34. Watson, J. G. and Chow, J. C., 2001, Source characterization of major emission source in the Imperial and Maxicali valleys along the US/Mexico boarder, Science of the Total Environment, 276, 33-47 https://doi.org/10.1016/S0048-9697(01)00770-7
  35. Zhao, W. and P. K. Hopke, 2004, Source apportionment for ambient particles in the San Gorgonio wilderness, Atmospheric Enνironment, 38, 5901-5910 https://doi.org/10.1016/j.atmosenv.2004.07.011