대한전기학회논문지:전기물성ㆍ응용부문C (The Transactions of the Korean Institute of Electrical Engineers C)

대한전기학회 (The Korean Institute of Electrical Engineers)
권호 표지

EQCM법을 이용한 자기조립된 Viologen 단분자막의 전기화학적 특성 연구

Study on Electrochemical Property of Self-Assembled Viologen Monolayers Using Electrochemical Quartz Crystal Microbalance (EQCM) Method

  • 이동윤 (동아대학 항만물류시스템학과) ;
  • 박상현 (동아대학 전기공학과) ;
  • 박재철 (영진전문대학 전자정보계열) ;
  • 권영수 (동아대학 전기공학과)
  • 발행 : 2006.03.01
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⟨ 이전 논문 다음 논문 ⟩

초록

We fabricated the monolayers onto QCM by self-assembly using viologen, which has been widely used as electron acceptor. A gold electrode of the QCM was cleaned by piranha solution and prepared the ethanol-acetonitrile(1:1) solution with 2 m mol/l viololgen compounding of pure hi gas. We determined the time dependence to resonant frequency shift during self-assembly process and the electrochemical behavior of the self-assembled viologen monolayers by cyclic voltammetry. With increasing scan rate, the redox peak current of the viologen increased linearly. This was signified that the redox reaction was reversible. The EQCM measurements revealed the anions transfer during redox reactions, respectively. From the EQCM data, the well-defined shape peaks were nearly equal charges by cyclic voltammetry.

키워드

참고문헌

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