Abstract
This stud y was conducted to investigate the bonding strength of plywood bonded with fatty acid-glycerol-pMDI adhesives with equivalent ratios of 1:1:2, 1:1:3, 1:1:4, 1:1:5, and 1:1:6. With veneer moisture contents of 0%, 3%, 5%, 8% and 15%, the bonding strengths exceeded the requirement of Korean plywood standard of $7.0kgf/cm^2$ with values of $13.7kgf/cm^2$, $11.6kgf/cm^2$, $11.2kgf/cm^2$, $9.8kgf/cm^2$, and $7.4kgf/cm^2$, respectively at fatty acid-glycerol-pMDI ratio of 1:1:2. With veneer moisture content of 30%, the bonding strengths exceeded th e requirement of Korean plywood standard of $7.0kgf/cm^2$, when fatty acid-glycerol-pMDI ratios were 1:6. Finally for satisfying the Korean plywood standard, the ratio of MDI in fatty acid-glycerol-pMDI should be increased with increasing of veneer moisture content.
본 연구는 단판 함수율을 0%, 3%, 5%, 8%, 15%, 30%로, 지방산: 글리세롤: MDI의 당량비율을 1:1:2, 1:1:3, 1:1:4, 1:1:5, 1:1:6 으로 달리하여 상태 (비내수)접착력을 조사하였다. 함수율 0%, 3%, 5%, 8%, 15%에서는 지방산 : 글리세롤 : MDI 당량비 1:1:2 일때, KS F 3101(보통합판) 기준 접착력 $7.0kgf/cm^2$를 상회하였으며, 함수율이 커질수록 접착력이 점차 감소하여 각각 $13.7kgf/cm^2$, $1.6kgf/cm^2$, $11.2kgf/cm^2$, $9.8kgf/cm^2$, $7.4kgf/cm^2$ 순으로 나타났다. 함수율 30% 에서는 지방산 : 글리세롤 : MDI 당량비 1:1:6 일 때, 강도 $8.1kgf/cm^2$로 KS 규격 접착력을 만족하였다. KS 규격 접착력을 만족시키기 위해서는 단판의 함수율이 증가할수록 MDI 비율을 높여야 한다.
