DOI QR코드

DOI QR Code

Effects of Added Silicone Oils on the Surface Hydrophobicity of Silicone Rubber

실리콘 고무의 소수성에 미치는 첨가된 실리콘 오일의 영향

  • 한동희 (한국전기연구원 재료응용연구단) ;
  • 조한구 (한국전기연구원 재료응용연구단) ;
  • 강동필 (한국전기연구원 재료응용연구단) ;
  • 민경은 (경북대학교 고분자공학과)
  • Published : 2006.01.01

Abstract

This paper reports on the effects of silicone oils, used as processing agents, on the recovery of hydrophobicity of silicone rubber. The recovery of hydrophobicity was evaluated by the measuring the contact angle, the surface electrical resistance and SEM. Here, we formed artificial contamination on the surface of samples, which scratched by sand papers and alumina powders. There was small recovery of hydrophobicity on the surface of SIR-A that silicone oil was not added. In both oil-added samples, SIR-B and SIR-C, recovery of hydrophobicity was achieved greatly. The surface of SIR-C showed that a lot of silicone oil was observed due to migration of oil, relatively in comparison with SIR-B. The tendency of recovery of hydrophobicity expressed by contact angle was in a good agreement with electrical property as determined by surface resistivity.

Keywords

References

  1. J. L. Goudie, 'Silicones for outdoor insulator maintenance', IEEE International Sym. on Electrical Insulation, p. 256, 2002
  2. CIGRE WG 22.03, 'Worldwide service experience with HV composite insulators', Electra, No. 191, p. 26, 2000
  3. Hackam, 'Outdoor HV Polymeric Insulators', Proceedings of 1998 ISEIM, p. 1, 1998
  4. H. Liu, G. Cash, D. Birtwhistle, and G. George, 'Characterization of a severely degraded silicone elastomer HV insulator-an aid to development of lifetime assessment techniques', IEEE Transactions on Dielectrics and Electrical Insulation, Vol. 12, p. 478, 2005 https://doi.org/10.1109/TDEI.2005.1453452
  5. H. Hillborg and U. W. Gedde, 'Hydrophobicity recovery of polydimethylsiloxane after exposure to corona discharges', Polymer, Vol. 39, No. 10, p. 1991, 1998
  6. 박영국, 이운석, 정수현, 장동욱, 임기조, '옥외 애자용 재료의 표면 전기전도 특성', 전기전자재료학회논문지, 11권, 10호, p. 758, 1998
  7. X. Wang, X. Liang, and Y. Zhou, 'Aging effect of UV radiation on SIR insulators' hydrophobicity property', CEIDP Annual Report, p. 241, 2004
  8. 허창수, 연복희, 조한구, 'HTV 실리콘 고무에서 열화인자에 따른 저분자량 성분과 표면 발수성의 변화', 전기전자재료학회논문지, 12권, 1호, p. 1, 1999
  9. D. H. Han, H. Y. Park, D. P. Kang, H. G. Cho, K. E. Min, K. Takasu, and T. Kuroyagi, 'Effects of added silicone oils on the surface characteristics of silicone rubber', IEEE Trans. on Dielectrics and Electrical Insulation, Vol. 9, No.2, p. 323, 2002
  10. K. Iida and R. Hackam, 'Low molecular weight of fluid in an alloy of EPDM/SIR', CEIDP Annual Report, p. 607, 2004
  11. H. Homma, T. Kuroyagi, and K. Izumi, 'Diffusion of low molecular weight siloxane from bulk to surface', IEEE Trans. on Dielectrics and Electrical Insulation, Vol. 6, No.3, p. 370, 1999
  12. F. Garbassi, M. Morra, and E. Occhiello, 'Polymer Surfaces from Physics to Technology', John Wiely & Sons Ltd., 1994