부탄의 직접분해로부터 수소 생산을 위한 카본블랙의 촉매적 작용

Catalysis of carbon black for hydrogen production by butane decomposition reaction

  • 윤석훈 (영남대학교 디스플레이화학공학부) ;
  • 한기보 (영남대학교 디스플레이화학공학부) ;
  • 박노국 (영남대학교 디스플레이화학공학부) ;
  • 류시옥 (영남대학교 디스플레이화학공학부) ;
  • 윤기준 (영남대학교 디스플레이화학공학부) ;
  • 한귀영 (영남대학교 디스플레이화학공학부) ;
  • 이태진 (영남대학교 디스플레이화학공학부)
  • 발행 : 2006.12.30

초록

The butane decomposition over the catalyst is an attractive method for the hydrogen production. The objective of the work was investigated the catalysis of carbon black in butane decomposition reaction. The Butane decomposition was performed over carbon black catalyst in a range of $500-1100^{\circ}C$. The butane conversion of thermal decomposition and catalytic decomposition were increased with increasing the reaction temperature The butane conversion of the thermal decomposition was higher than the butane conversion of the catalytic decomposition. Hydrogen and methane were mostly observed in the butane decomposition over $1000^{\circ}C$. Especially, the hydrogen yield was steadily increased with raising the reaction temperature, It could be known that the hydrogen yield of the catalytic decomposition was higher than one of the thermal cracking because the hydrogen productivity was improved by the catalyst. The deactivation of the catalyst was not observed in the reactivity test. The surface and crystalline of the fresh and used catalysts were characterized by TEM, BET surface area and XRD analysis, respectively. The fresh carbon black particles had mostly smoothly round-shaped surfaces. In the surface of the carbon black after the reaction, the deposited carbon was formed as the protrusion-shaped carbon and the cone-shaped. The proper peaks of carbon black appeared in XRD analysis.

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