• Title/Summary/Keyword: 부탄

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Evaluation of Extractants for Bio-butanol Extraction Fermentation Using Organic Solvents and Ionic Liquids (유기용매와 이온성액체를 이용한 바이오 부탄올 추출발효 용매 선정 평가)

  • Cho, Min-Ok;Lee, Sun-Mi;Sang, Byoung-In;Um, Young-Soon
    • KSBB Journal
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    • v.24 no.5
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    • pp.446-452
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    • 2009
  • Oleyl alcohol, butyl butyrate, and two different ionic liquids were evaluated for the extraction of butanol from culture broth without toxic effect to cells. The tested solvents showed more than 50% extraction efficiency, and oleyl alcohol was chosen as the best extractant for butanol among the used extractants with a partition coefficient of 2.89. When oleyl alcohol was used as an extractant, more than 80% of butanol was extracted in the wide range of butanol concentrations (1-20 g/L) and pH values (pH 4-5.5). In extractive fermentation using oleyl alcohol only, there was 11% more butanol production and glucose consumption when compared to that without extractive fermentation, implicating a reduced inhibitory effect of butanol due to butanol removal to the oleyl alcohol phase. In addition, oleyl alcohol did not inhibit cell growth, while a mixture of oleyl alcohol and butyl butyrate with the volume ratio of 9:1~7:3 inhibited either butanol production or cell growth significantly due to the toxicity of butyl butyrate to cells. In conclusion, oleyl alcohol can be used as an efficient and non-toxic solvent for extractive fermentation for butanol production.

Pervaporative Recovery of Bio-butanol through Dense- and Composite-type PDMS Membranes (PDMS막을 이용한 바이오 부탄올 분리정제와 투과증발 특성에 관한 연구)

  • Kim, Jeong-Hoon;Ryu, Bi-Ho;Chang, Bong-Jun;Kim, Woo-Nyon
    • Membrane Journal
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    • v.19 no.2
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    • pp.157-164
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    • 2009
  • Bio-butanol recovery by pervaporation was performed with dense and composite polydimethylsiloxane (PDMS) membranes. The pervaporative behavior of the membranes was investigated as a function of operation temperature $(20{\sim}40^{\circ}C)$ and membrane thickness $(100{\sim}1{\mu}m)$ using a series of aqueous BtOH model solutions $(1{\sim}5wt%)$. With the increment of the BtOH concentration in feed, the Butanol concentration in permeate, pervaporation selectivity of Butanol over water and Butanol permeation flux increased. As the operating temperature of feed solutions increased, the BtOH concentration in permeate, pervaporation selectivity and permeation flux increased markedly. As the thickness of the PDMS membrane decreased, permeation flux increased but pervaporation selectivity decreased. These results were explained in terms of high solubility and low diffusion resistance of BtOH over water toward hydrophobic and rubbery PDMS membranes.

Clostridium acetobutylicum B18를 이용한 부탄올 발효에서 pH 및 extra nutrient가 부탄올 생성에 미치는 영향연구

  • Yun, Ji-Yong;Kim, Tae-Yong;Park, Chan-El;Park, Chang-Ho
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.243-246
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    • 2000
  • Clostridium acetobutylicum Bl8 can produce a large amount of butanol by control characteristics such as glucose concentration, pH and extra nutrient. It is known that this stain is potentially useful in simultaneous ABE fermentation-seperation system because of its low acid $production^{1).}$ The purpose of this study is to determine optimal condition of fermentation to produce maximum butanol in batch and fed-batch by strain Bl8.

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가정용부탄 특소세 환급안내

  • Korea LPGas Industry Association
    • LP가스
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    • s.78
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    • pp.62-68
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    • 2002
  • 이 내용은 지난 1월 9일 재정경제부와 국세청, 산업자워부가 수도권 가정용부탄 충전사업자를 대상으로 협회 회의실에서 실시한 "가정용부탄 특소세 환급교육" 자료이다.

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Butanol Separation/Concentration by Plasma Treated Pervaporation Membrane (저온 플라즈마 처리된 투과증발막의 부탄올 분리/농축 연구)

  • 김현영;임군택;김성수
    • Membrane Journal
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    • v.10 no.4
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    • pp.198-204
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    • 2000
  • Pervaporation membranes were fabricated by low temperature plasma treatment the concentrate butanol solution from fermentation process. Effects of power, reaction time, and monomer flow rate were examined to optimize the (W!FM)t value as 4.0389 x 109 J . min/kg. Various organic compounds were tested in plasma treatment. Contact angle and relative sorption ratio were examined in terms of membrane performance. With the increase of contact angle and relative sorption ratio separation factor was enhanced from 0.186 to 3.525. and butanol flux increased from 0.042 to 0.567 kglm2. hr. Hydrophobicity of the membrane increased the affinity with butanoL Heat of mixing for monomer with butanol was examined, but failed to find the trend, because plasma polymerization of monomer produced the new compounds much different from monomers.

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Catalysis of carbon-black for hydrogen production by butane decomposition reaction (부탄의 직접분해로부터 수소 생산을 위한 카본블랙의 촉매적 작용)

  • Yoon, Suk-Hoon;Han, Gi-Bo;Park, No-Kuk;Ryu, Si-Ok;Lee, Tae-Jin;Yoon, Ki-June;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.380-383
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    • 2006
  • 수소는 미래의 청정에너지원이다. 수소를 생산하는 효과적인 방법으로는 탄소계촉매를 이용하여 부탄을 분해하는 것이다. 촉매는 카본블랙이 사용되었으며, $500{\sim}1100^{\circ}C$의 온도 범위에서 열분해 반응과 촉매분해반응이 수행되었다. 열분해의 경우 온도가 증가함에 따라 전화율이 증가하여 $800^{\circ}C$에서 98.9%로 부탄이 거의 분해되었으며, $900^{\circ}C$ 이상의 온도에서는 전화율이 100%까지 도달하였다. 부탄 분해반응에서 기대되는 생성물은 메탄, 에틸렌, 에탄, 프로필렌, 프로판 등이다. $1000^{\circ}C$이상의 온도에서는 부탄 촉매 분해반응에서 거의 대부분 수소와 메탄만이 관찰되었다. 특히 $500-1100^{\circ}C$까지 온도가 증가하였을 때 수소의 생성율은 꾸준히 증가하는 것으로 확인되었고 촉매분해반응이 촉매를 사용하지 않은 열분해반응보다 온도가 증가함에 따라 수소의 선택도를 더욱 향상시켜 보다 많은 수소가 생성되었으며, 반응성 실험이 진행되는 동안 촉매의 비활성화는 관찰되지 않았다. 반응전후의 촉매의 특성을 분석하기 위해 TEM 및 SEM 분석을 하였다. 반응전의 촉매는 매끈한 모양이었으나 $1000-1100^{\circ}C$에서 반응후에는 표면에 돌기모양을 형성하는 것을 관찰할 수 있었다.

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Safety Evaluation of Non-refillable Butane Can Equipped with Relief Valve for Prevention of Explosion (안전밸브가 장착된 휴대용 부탄캔에 대한 안전성 평가 연구)

  • Kang, Seung-Kyu;Choi, Kyung-Suhk
    • Journal of Energy Engineering
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    • v.17 no.4
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    • pp.212-217
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    • 2008
  • This study carried out the safety evaluation of non-refillable butane can for portable gas range equipped with relief valve for prevention of explosion. The can is heated by electric heater at the real using condition and the extreme condition after installing at a portable gas range for checking the operating pressure and the evaluating suitability of releasing flux. And the possibility of fire or explosion was tested when the gas was released from the relief valve at the real condition. As a result of this safety evaluation test, a non-refillable butane can with relief valve prevents the can from exploding by control of internal pressure.

The History and Performative Aspect of Bhutan Paro Tshechu (부탄 파로 체추 <참>의 역사와 연행양상)

  • Jeon, Kyung-Wook
    • (The) Research of the performance art and culture
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    • no.37
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    • pp.327-363
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    • 2018
  • Bhutan's mask dance drama, Cham is performed in the festival of Tshechu. Originating from the 17th century, Tschechu is a religious ritual as well as a traditional festival held to commemorate the birth of Padmasambhava, who spread Buddhism in the kingdom of Bhutan. Bhutanese Cham and Tibetan Cham share similar traits in their content of , , and in their characters of Pawo and Pamo. Meanwhile, , , , , , , , are distinctive performances of Bhutanese cham. Moreover, the clown character Atsara in Bhutanese cham is a character that does not appear in the Tibetan Cham. Atsara, a humorous character, can be identified by its use of a long phallus ornament on the head or by a distorted face mask with a phallus in its hand. Bhutanese Cham, originally from Tibet, is a religious mask dance drama handed down in Lamaism temples. In later generations, new performances reflective of Bhutan's history, myth, legends, and religion were added in large amount. Thus, the Cham of Bhutan now has very independent and characteristic aspects.

Antioxidative and Nitrite-scavenging Activities of Edible Mushrooms (버섯류의 항산화성 및 아질산염 소거작용)

  • Lee, Gee-Dong;Chang, Hak-Gil;Kim, Hyun-Ku
    • Korean Journal of Food Science and Technology
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    • v.29 no.3
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    • pp.432-436
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    • 1997
  • This study was conducted to investigate the functional characteristics of diethylether and butanol extracts from Ganoderma lucidum, Agaricus bisporus and Lentinus edodes. Electron donating abilities of diethylether and butanol extracts from Ganoderma luculum were 95.07% and 97.75%, respectively. Electron donating abilities of butanol extracts from Agaricus bisporus was 94.33%, and that of Lentinus edodes was 96.09%. Antioxidative activities of diethylether and butanol extracts from Canoderma lucidum were higher than those of BHA. All extracts of Agaricus bisporus and Lentinus edodes showed lower antioxidative activity than that of BHA. Nitrite-scavenging abilities of diethylether and butanol extracts from Ganoderma lucidum were 68.34% and 44.44%, respectively. Nitrite-scavenging abilities of butanol extracts from Agaricus bisporus were 43.39%, and those of Lentinus edodes were 68.23%.

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Isolation, Identification and Mutant Development of Butanol Tolerance Bacterium (부탄올 내성 미생물의 분리, 동정 및 변이주의 개발)

  • Jung, Hyesook;Lee, Jinho
    • Microbiology and Biotechnology Letters
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    • v.41 no.1
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    • pp.26-32
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    • 2013
  • Butanol-resistant bacteria were isolated from butanol solvent. The cell growth of isolated strains declined with increasing concentrations of butanol, and isolated strain BRS02 displayed more resistance to 12.5 g/L of butanol than other isolated strains. In addition, strain BRS251, which was resistant to even higher concentrations of butanol, was developed by the mutation of BRS02 using UV. BRS251 could grow in LB medium containing up to 17.5 g/L of butanol, 32.5 g/L of propanol, or 6 g/L of pentanol, whereas the control strain Escherichia coli was found to be tolerant to 7.5 g/L of butanol, 20 g/L of propanol, or 2 g/L of pentanol. The isolated BRS02, a Gram(+) bacterium seen to have a cocci form under the microscope, grew in 6.5% NaCl. According to biochemical tests, BRS02 can metabolize and produce acid with D-galactose, D-maltose, D-mannitol, D-mannose, methyl-${\beta}$-Dglucopyranoside, D-ribose, sucrose, or D-trehalose, as carbon sources. Also, this strain showed resistance to bacitracin, vibriostatic agent O/129, and optochin, alongside positive activities for arginine dihydrolase, ${\alpha}$-glucosidase, and urease. The BRS02 strain was identified as Staphylococcus sp. by analyses of the 16S rRNA gene, phylogenetic tree, and biochemical tests.