Preparation and Characteristics of Anionic Surfactant Using Waste Fleshing Scrap

피혁 제조 공정 중 발생하는 폐돈지를 이용한 음이온성 계면활성제 제조 및 특성

  • 신수범 (한국신발.피혁연구소 동두천피혁분소) ;
  • 민병욱 (한국신발.피혁연구소 동두천피혁분소) ;
  • 양승훈 (한국신발.피혁연구소 동두천피혁분소) ;
  • 박민석 (한국신발.피혁연구소 동두천피혁분소) ;
  • 원기천 (SM 소프랜드) ;
  • 백두현 (충남대학교 섬유공학과)
  • Published : 2006.12.27

Abstract

Study has been made for producing anionic surfactant using waste fleshing scraps from the leather making process through refining, esterification, sulfonation and blending processes. As a most optimum lard oil refining method, refining was carried out for 4 hours under temperature of $120^{\circ}C$ and approximately 200 mbar vacuum, which gave a recovery of more than 80% lard oil. Refined lard oil obtained thus was undergone methlyl-esterification, then sulfonated to make a degreasing agent. By methyl-esterification using lard oil, more than 85% of fatty acid and $12{\sim}13%$ of glycerine were extracted from the oil. Sulfonation of the extracted fatty acid ester lard oil has shown most optimum at $15{\sim}20%$ chlorosulfonic acid content, and the content of bonding sulfate at this time was higher than 3.5%. Finally the followed anionic surfactant having degreasing force of 80% and higher could be made by blending process.

Keywords

References

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