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Effect of Dispersed MoO3 Amount on Catalytic Activity of NiO-ZrO2 Modified with MoO3 for Acid Catalysis

  • Sohn, Jong-Rack (Department of Applied Chemistry, Engineering College, Kyungpook National University) ;
  • Lee, Sung-Gyu (Department of Applied Chemistry, Engineering College, Kyungpook National University) ;
  • Shin, Dong-Cheol (Department of Applied Chemistry, Engineering College, Kyungpook National University)
  • Published : 2006.10.20

Abstract

NiO supported on zirconia modified with $MoO_3$ for acid catalysis was prepared by drying powdered $Ni(OH)_2-Zr(OH)_4$ with ammonium heptamolybdate aqueous solution, followed by calcining in air at high temperature. The characterization of prepared catalysts was performed using FTIR, Raman, XRD, and DSC. $MoO_3$ equal to or less than 15 wt% was dispersed on the surface of catalyst as two-dimensional polymolybdate or monomolybdate, while for $MoO_3$ above 15 wt%, crystalline orthorhombic phase of $MoO_3$ was formed, showing that the critical dispersion capacity of $MoO_3$ on the surface of catalyst is 0.18 g/g NiO-$ZrO_2$ on the basis of XRD analysis. Acidity and catalytic activities for acid catalysis increased with the amount of dispersed $MoO_3$. The high acid strength and acidity was responsible for the Mo=O bond nature of the complex formed by the interaction between $MoO_3$ and $ZrO_2$. The catalytic activity for acid catalysis was correlated with the acidity of the catalysts measured by the ammonia chemisorption method.

Keywords

References

  1. Wainwright, M. S.; Foster, N. R. Catal. Rev. 1979, 19, 211 https://doi.org/10.1080/03602457908068056
  2. Dadyburjor, D. B.; Jewur, S. S.; Ruckenstein, E. Catal. Rev. 1979, 19, 293 https://doi.org/10.1080/03602457908068057
  3. Sohn, J. R. J. Ind. Eng. Chem. 2004, 10, 1
  4. Cheung, T. K.; dItri, J. L.; Lange, F. C.; Gates, B. C. Catal. Lett. 1995, 31, 153 https://doi.org/10.1007/BF00808829
  5. Tanabe, K.; Misono, M.; Ono, Y.; Hattori, H. New Solid Acids and Bases; Elsevier Science: Amsterdam, 1989; Chapter 4
  6. Arata, K. Adv. Catal. 1990, 37, 165 https://doi.org/10.1016/S0360-0564(08)60365-X
  7. Ward, D. A.; Ko, E. I. J. Catal. 1994, 150, 18 https://doi.org/10.1006/jcat.1994.1319
  8. Kustov, L. M.; Kazansky, V. B.; Figueras, F.; Tichit, D. J. Catal. 1994, 150, 143 https://doi.org/10.1006/jcat.1994.1330
  9. Hsu, C. Y.; Heimbuch, C. R.; Armes, C. T.; Gates, B. C. J. Chem. Soc., Chem. Commun. 1992, 1645
  10. Cheung, T. K.; Gates, B. C. J. Catal. 1997, 168, 522 https://doi.org/10.1006/jcat.1997.1654
  11. Coelho, M. A.; Resasco, D. E.; Sikabwe, E. C.; White, R. L. Catal. Lett. 1995, 32, 253 https://doi.org/10.1007/BF00813219
  12. Hosoi, T.; Shimadzu, T.; Ito, S.; Baba, S.; Takaoka, H.; Imai, T.; Yokoyama, N. Prepr. Symp. Div. Petr. Chem.; American Chemical Society: LosAngels, CA, 1988; p 562
  13. Ebitani, K.; Konishi, J.; Hattori, H. J. Catal. 1991, 130, 257 https://doi.org/10.1016/0021-9517(91)90108-G
  14. Hua, W.; Xia, Y.; Yue, Y.; Gao, Z. J. Catal. 2000, 196, 104 https://doi.org/10.1006/jcat.2000.3032
  15. Moreno, J. A.; Poncelet, G. J. Catal. 2001, 203, 453 https://doi.org/10.1006/jcat.2001.3324
  16. Sohn, J. R.; Cho, E. S. Appl. Catal. A : Gen. 2005, 282, 147 https://doi.org/10.1016/j.apcata.2004.12.007
  17. Larsen, G.; Lotero, E.; Parra, R. D. In Proceeding of the 11th International Congress on Catalysis; Elsevier: New York, 1996; pp 543-551
  18. Hino, M.; Arata, K. J. Chem. Soc., Chem. Commun. 1987, 1259
  19. Sohn, J. R.; Chun, E. W.; Pae, Y. I. Bull. Korean Chem. Soc. 2003, 24, 1785 https://doi.org/10.5012/bkcs.2003.24.12.1785
  20. Brown, A. S. C.; Hargreaves, J. S. J.; Taylor, S. H. Catal. Letts. 1999, 57, 109 https://doi.org/10.1023/A:1019047632335
  21. Sohn, J. R.; Lee, S. H. Appl. Catal. A: Gen. 2004, 266, 89 https://doi.org/10.1016/j.apcata.2004.01.034
  22. Sohn, J. R.; Han, J. S. J. Ind. Eng. Chem. 2005, 11, 439
  23. Sohn, J. R.; Han, J. S.; Kim, H. W.; Pae, Y. I. Bull. Korean Chem. Soc. 2005, 26, 755 https://doi.org/10.5012/bkcs.2005.26.5.755
  24. Larsen, G.; Lotero, E.; Petkovic, L. M.; Shobe, D. S. J. Catal. 1997, 169, 67 https://doi.org/10.1006/jcat.1997.1698
  25. Afanasiev, P.; Geantet, C.; Breysse, M.; Coudurier, G.; Vedrine, J. C. J. Chem. Soc., Faraday Trans. 1994, 190, 193
  26. Sohn, J. R.; Kim, Y. T.; Shin, D. C. Bull. Korean Chem. Soc. 2005, 26, 1479
  27. Sohn, J. R.; Cho, S. G.; Pae, Y. I.; Hayashi, S. J. Catal. 1996, 159, 170 https://doi.org/10.1006/jcat.1996.0076
  28. Liu, Z.; Chen, Y. J. Catal. 1998, 177, 314 https://doi.org/10.1006/jcat.1998.2123
  29. Zhao, B.; Wang, X.; Ma, H.; Tang, Y. J. Mol. Catal. A: Chem. 1996, 108, 167 https://doi.org/10.1016/1381-1169(96)00008-8
  30. Chen, K.; Xie, S.; Iglesia, E.; Bell, A. T. J. Catal. 2000, 189, 421 https://doi.org/10.1006/jcat.1999.2720
  31. Smith, M. R.; Ozkan, U. S. J. Catal. 1993, 141, 124 https://doi.org/10.1006/jcat.1993.1124
  32. Mestl, G.; Srinivasan, T. K. K. Cat. Rev. Sci. Eng. 1998, 40, 451 https://doi.org/10.1080/01614949808007114
  33. Dufresne, P.; Payen, E.; Grimblot, J.; Bonnelle, J. P. J. Phys.Chem. 1981, 85, 2344 https://doi.org/10.1021/j150616a010
  34. Hu, H.; Wachs, I. E. J. Phys. Chem. 1995, 99, 10897 https://doi.org/10.1021/j100027a034
  35. Roark, R. D.; Kohler, S. D.; Ekerdt, J. G.; Kim, D. S.; Wachs, I. E. Catal. Lett. 1992, 16, 77 https://doi.org/10.1007/BF00764357
  36. Schild, C. H.; Wokaun, A.; Köppel, R. A.; Baiker, A. J. Catal. 1991, 130, 657 https://doi.org/10.1016/0021-9517(91)90145-T
  37. Sohn, J. R.; Doh, I. J.; Pae, Y. I. Langmuir 2002, 18, 6280 https://doi.org/10.1021/la020223y
  38. Scheithauer, M.; Grasselli, R. K.; Knozinger, H. Langmuir 1998, 14, 3019 https://doi.org/10.1021/la971399g
  39. Xie, Y. C.; Tang, Y. Q. Adv. Catal. 1990, 37, 1 https://doi.org/10.1016/S0360-0564(08)60362-4
  40. Litteti, L.; Nova, I.; Ramis, G.; DallAcqua, L.; Busca, G.; Giamello, E.; Forzatti, P.; Bregani, F. J. Catal. 1999, 187, 419 https://doi.org/10.1006/jcat.1999.2603
  41. Sohn, J. R.; Lim, J. S. Catal. Today 2006, 111, 403 https://doi.org/10.1016/j.cattod.2005.10.052
  42. Sohn, J. R.; Han, J. S. Appl. Catal. A: Gen. 2006, 298, 168 https://doi.org/10.1016/j.apcata.2005.09.033
  43. Olah, F. G. A.; Prakash, G. K. S.; Sommer, J. Science 1979, 206, 13 https://doi.org/10.1126/science.206.4414.13
  44. Tanabe, K.; Misono, M.; Ono, Y.; Hattori, H. New Solid Acids and Bases; Elsevier Science: Amsterdam, 1989; p 185
  45. Sohn, J. R.; Ryu, S. G. Langmuir 1993, 9, 126 https://doi.org/10.1021/la00025a029
  46. Basila, M. R.; Kantner, T. R. J. Phys. Chem. 1967, 71, 467 https://doi.org/10.1021/j100862a001
  47. Satsuma, A.; Hattori, A.; Mizutani, K.; Furuta, A.; Miyamoto, A.; Hattori T.; Murakami, Y. J. Phys. Chem. 1988, 92, 6052 https://doi.org/10.1021/j100332a042
  48. Decanio, S. J.; Sohn, J. R.; Fritz, P. O.; Lunsford, J. H. J. Catal. 1986, 101, 132
  49. Tanabe, K. Solid Acids and Bases; Kodansha: Tokyo, 1970; p 103
  50. Sohn, J. R.; Park, W. C. Appl. Catal. A: General 2003, 239, 269 https://doi.org/10.1016/S0926-860X(02)00392-7
  51. Sohn, J. R.; Ozaki, A. J. Catal. 1980, 61, 29 https://doi.org/10.1016/0021-9517(80)90336-X
  52. Pae, Y. I.; Bae, M. H.; Park, W. C.; Sohn, J. R. Bull. Korean Chem. Soc. 2004, 25, 1881 https://doi.org/10.5012/bkcs.2004.25.12.1881

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