Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Salphen H2 as a Neutral Carrier for the Uranyl Ion-Selective PVC Membrane Sensor

  • Kim, Dong-Wan (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Park, Kyeong-Won (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Yang, Mi-Hyi (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Kim, Jin-eun (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Lee, Shim-Sung (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University) ;
  • Kim, Jae-Sang (Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University)
  • Published : 2006.06.20
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Abstract

The complexation of N,N'-4,5-(ethylenedioxy)benzenebis(salicylideneimine), (salphen$H_2$) with uranyl ion was studied in acetonitrile solution spectrophtometrically, and the formation constant of the resulting 1 : 1 complex was evaluated. The salphen$H_2$ ligand was used as an ionophore in plasticized poly(vinyl chloride) (PVC) matrix membrane sensor for uranyl ion. The prepared sensors exhibited a near Nernstian response, 28.0-30.9 mV/decade for uranyl ion over the concentration range $1.0\;{\times}\;10^{-2}$ to $1.0\;{\times}\;10^{-6}$M with a limit of detection of $3.2\;{\times}\;10^{-7}$ M. The proposed electrode could be used at a working pH range of 1.5 - 4.0.

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