Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Assignment of Vibronic Emission Spectra of Jet-Cooled m-Tolunitrile

  • Park, Chan Ho (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University) ;
  • Lee, Sang-Kuk (Department of Chemistry and The Chemistry Institute for Functional Materials, Pusan National University)
  • Published : 2006.09.20
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Abstract

The technique of corona-excited supersonic expansion was applied to produce electronically excited but rovibrationally cooled m-tolunitrile. The well-resolved vibronic emission spectrum of the jet-cooled m-tolunitrile in the $S_1\;\rightarrow \;S_0$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. From an analysis of the spectrum observed, it was confirmed that the electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined.

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