Bulletin of the Korean Chemical Society

  • 제27권12호
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  • Pages.1985-1988
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  • 2006
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Polymeric Iodide-ion Selective Electrodes Based on Urea Derivative as an Ionophore

  • Jeong, Dae-Cheol (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Lee, Hyo-Kyoung (Department of Chemistry and Institute of Basic Science, Chonnam National University) ;
  • Jeon, Seung-Won (Department of Chemistry and Institute of Basic Science, Chonnam National University)
  • 발행 : 2006.12.20
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초록

The polymeric membrane electrodes based on urea derivative as an ionophore were prepared and studied for the iodide-ion selective electrode. This membrane exhibits a linear stable response over a wide concentration range ($1.0\;{\times}\;10^{-5}\sim1.0\;{\times}\;10^{-2}$) with a slope of -57.7 mV/decade, a detection limit of log[$I^-$] = -5.63, and a selectivity coefficient for iodide against perchlorate anion (log$K^{pot}_{I^-,j}$ = -1.42). The selectivity series of the membrane gives the follow as $I^-$ > $SCN^-$, $Sal^-$ > $ClO_4^-$ > $NO_3^-$ > $Br^-$ > $NO_2^-$ > $Cl^-$ > $F^-$. The proposed electrode showed good selectivity and response for iodide anion over a wide variety of other anions in pH 5.0 buffer solutions.

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피인용 문헌

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  2. Electrosynthesis of Layered Organo-Manganese Dioxide Framework-Doped with Cobalt for Iodide Sensing vol.33, pp.19, 2017, https://doi.org/10.1021/acs.langmuir.7b00419
  3. Highly selective solid-state sensor for iodide based on the combined use of platinum (IV) phthalocyanine and solidified pyridinium ionic liquid pp.1433-0768, 2019, https://doi.org/10.1007/s10008-018-4159-9
  4. Potentiometric Iodide Selectivity of Polymer‐Membrane Sensors Based on Co(II) Triazole Derivative vol.20, pp.13, 2008, https://doi.org/10.1002/elan.200704197
  5. Electrochemical determination of iodide by poly(3-aminophenylboronic acid) film electrode at moderately low pH ranges vol.687, pp.2, 2006, https://doi.org/10.1016/j.aca.2010.12.019
  6. Iodide selective membrane electrodes based on a Molybdenum–Salen as a neutral carrier vol.31, pp.8, 2006, https://doi.org/10.1016/j.msec.2011.06.006
  7. Selective Sorption of Iodide onto Organo-MnO<sub>2</sub> Film and Its Electrochemical Desorption and Detection vol.877, pp.None, 2006, https://doi.org/10.1016/j.aca.2015.03.041
  8. Electrochemical Anion Sensing: Supramolecular Approaches vol.120, pp.3, 2006, https://doi.org/10.1021/acs.chemrev.9b00624