자원리싸이클링 (Resources Recycling)

  • 제14권1호
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  • Pages.47-54
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  • 2005
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  • 2765-3439(pISSN)
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  • 2765-3447(eISSN)
한국자원리싸이클링학회 (The Korean Institute of Resources Recycling)
권호 표지

포도씨를 再活用한 活性炭의 製造

Preparation of Activated Carbon by Recycling of Waste Grape-seed

  • 발행 : 2005.02.01
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⟨ 이전 논문 다음 논문 ⟩

초록

본 연구에서는 농산물 폐기물인 국산 포도씨를 원료로 사용하여 roasting, cabonization, chemical activation 과정을 각각 거쳐 활성탄을 제조하였다. 화학적 활성화는 NaOH, KOH, ZnCl$_2$를 활성화제로 사용하였다. 100-300wt%의 중량비율로 활성화하여 제조된 활성탄의 N$_2$-BET 비표면적은 44.09~121.33 m$^2$/g으로 측정되었다. 포도씨 활성탄에 메틸렌 블루를 흡착 시킨 후 UV spectrometer를 사용하여 투광도를 측정하였으며, 투광도 측정 시 메틸렌 블루의 최대 흡광파장은 660 nm로 설정하였다. 그 결과 메틸렌블루의 흡착은 NaOH 활성화제를 사용하여 제조한 활성탄에서 가장 잘 이루어졌으며, 평형 흡착 시간은 60분인 것으로 나타났다.

Korean grape-seed that is one of the agricultural waste was used as a raw material to prepare activated carbon through roasting, carbonization and chemical activation processes. NaOH, KOH, ZnCl$^2$ were also used as activation reagents. The mixing of the ratios of the grape-seed and each activation reagent were varied to 100-300 weight percent. The surface areas of the activated carbon manufacture from the grape-seed were 44.09~121.33 m$^2$/g. The adsorbate transmittance of methylene blue was determined UV absorption at 660 nm as maximum adsorption wavelength using by UV spectrophotometer. As a result, adsorption of methylene blue on the activated carbon prepared with NaOH activation was more successful than others. Equilibrium absorption time was approximately 60 min.

키워드

참고문헌

  1. You, S. H., Kim, H. S., Kim, H. H., 1997: Adsorption of Chromium by Heat-treated Microporous Carbon, J. of Korean Ind. & Eng. Chem., 8, p.631
  2. Ahmadpour, A. and Do, D. D., 1996: Carbon, 34, p.471 https://doi.org/10.1016/0008-6223(95)00204-9
  3. Ferro-Gracia, M. A. et al., 1988: Carbon, 26, p.363 https://doi.org/10.1016/0008-6223(88)90228-X
  4. Hey, M., Marsh, H. and Reinoso, F. R., 1973: Carbon, 11, p.633 https://doi.org/10.1016/0008-6223(73)90330-8
  5. Martin-Gullon, I., Asensio, M., and Marcilla, R. Font., 1996: Carbon, 34, p.1515 https://doi.org/10.1016/S0008-6223(96)00106-6
  6. Tsai, W. T., Chang, C. Y. and Lee, S. L., 1998: Carbon, 35, p.1198 https://doi.org/10.1016/S0008-6223(97)84654-4
  7. Gergova, K. and Eser, S., 1996: Carbon, 34, p.879 https://doi.org/10.1016/0008-6223(96)00028-0
  8. Salvador, F. and Sanchez Jimenez, C., 1996: Carbon, 34, p.511 https://doi.org/10.1016/0008-6223(95)00211-1
  9. Kdlec, O., Varhanivova, A. and Zukal, A., 1970: Carbon, 8, p.321 https://doi.org/10.1016/0008-6223(70)90072-2
  10. Hwang. J. T., Kang, H. C., Kim. T. S. and Park. W. J.. 1999: Lipid Componant ami Properties of Grapr Seed Oils, Korean J. Food & Nutr., 7. p.831
  11. Henry R. Bungry, Energy, 1980: The Biomass Option. Wiley, New York
  12. Park. J. L. and Lee, S. H., 2000: Investigation (if Manufacturing the activated carhon from domestic rice hulls, J. Korean Environ. Admin., 6, p.179
  13. Kim, K. S., 1996: Experimental preparations of activated carbon from rice-hull, J. of Korean Soc. of Environ. Eng., 18, p.1313
  14. Lua, A. C. and Guo, J., 2001: Preparation and characterization of activated carbons from oil-palm stones fro gas-phase adsorption, Colloids and surface A: Physicochemi. and Eng. Aspects, p.179
  15. Kim, H. H., Park, S. K. and Kim, H. S., 1998: Preparation of activated coffee char by KOH activation, Applied Chem., 2, p.1048
  16. Barunauer, S. et al., 1940: Chem. Soc. 62. p.1723 https://doi.org/10.1021/ja01864a025
  17. Lee, J. M., Kim, H. H. and Chung, M. K., 2002: J. of Korean Ind. Eng. Chem. 13, p.156
  18. Lee, J. M., Kim, H. H., Chung, M. K.. 2002: Adsorption or Methylene Blue and Phenol from Aqueous Solution on to Activated Carbon, Applied Chem., 6, p.951
  19. Langmuir, I. and Am, J., 1918: Chem. Soc., 40, p.1361 https://doi.org/10.1021/ja02242a004