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Efficiency Improvement of Organic Light-emitting Diodes depending on Thickness of Hole Injection Materials

  • Kim, Weon-Jong (Department of Electrical Engineering, Kawngwoon University) ;
  • Yang, Jae-Hoon (Department of Electrical Engineering, Kawngwoon University) ;
  • Kim, Tag-Yong (Department of Electrical Engineering, Kawngwoon University) ;
  • Jeong, Joon (Department of Electrical Engineering, Kawngwoon University) ;
  • Lee, Young-Hwan (Department of Electrical Engineering, Kawngwoon University) ;
  • Hong, Jin-Woong (Department of Electrical Engineering, Kawngwoon University) ;
  • Park, Ha-Yong (Department of Electrical Engineering, Samcheok National University) ;
  • Kim, Tae-Wan (Department of Physics, Hongik University)
  • 발행 : 2005.10.01

초록

In the device structure of ITO/hole injection layer/N, N'-biphenyl-N, N'-bis-(1-naphenyl)-[1,1'-biphenyl]4,4'-diamine(NPB)/tris(8-hydroxyquinoline) aluminum$(Alq_3)/Al$, we investigated an effect of hole-injection materials (PTFE, PVK) on the electrical characteristics and efficiency of organic light-emitting diodes. A thermal evaporation was performed to make a thickness of NPB layer with a evaporation rate of $0.5\~1.0\;\AA/s$ in a base pressure of $5\times10^{-6}$ Torr. We measured current-voltage characteristics and efficiency with a thickness variation of hole-injection layer. The PTFE and PVK hole-injection layer improve a performance of the device in several aspects, such as good mechanical junction, reducing the operating voltage and energy band adjustment. Compared with the devices without a hole-injection layer, we have obtained that an optimal thickness of NPB was 20 nm in the device structure of $ITO/NPB/Alq_3/Al$. And using the PTFE or PVK hole-injection layer, the external quantum efficiencies of the devices were improved by $24.5\%\;and\;51.3\%$, respectively.

키워드

참고문헌

  1. G. B. Blanchet, Y. L. Loo, J. A. Rogers, F. Gao, and C. R. Fincher, 'Large area, high resolution, dry printing of conducting polymers for organic electronics', Applied Physics Letters, 82, p. 463, 2003
  2. H. E. A. Huitema, G. H. Gelinck, J. B. P. H. Vander, K. M. Hart, E. Cantatore, and D. M. de Leeuw, 'Active-matrix displays driven by solution processed polymeric transistors', Advanced Materials, 14, p. 201, 2002
  3. L. S. Hung and C. H. Chen, 'Recent progress of molecular organic electroluminescent materials and devices', Materials Science and Engineering, R. 39, p. 143, 2002
  4. M. Pope, H. P. Kallmann, and P. Magnante, 'Electroluminescence in organic crystals', J. Chem. Phy., 38, p. 2042, 1963
  5. W. Helfrich and W. G. Schneider, 'Recombination radiation in anthracene crystals', Phys. Rev. Lett., 14, p.229, 1965
  6. R. H. Friend, R. W. Gymer, A. B. Holmes, J. H. Burroughes, R. N. Marks, C. Taliani, D. C. Bradley, D. A. Dos Santos, J. L. Bredas, M. Logdlund, and W. R. Saraneck, 'Electroluminescence in conjugated polymer', Nature, Vol. 397, p. 121, 1999
  7. K. Kudo, 'Organic light emitting transistors', Current Applied Physics, Vol. 5, p. 337, 2005
  8. C. Jiang, W. Yang, J. Peng, S. Xiao, and Y. Caoet, 'High-efficiency, saturated red-phosphorescent polymer light-emitting diodes based on conjugated and non-conjugated polymers doped with an Ir complex', Advanced Materials, Vol. 16, No.6, p. 537, 2004
  9. H. S. Lee, K. W. Jang, M. K. Choi, S. I. Lee, T. W. Kim, M. Iwamoto, arid J. U. Lee, 'Inelastic electron tunneling in Au/polymide/monolayer organic film/Pb structures using a polyimide barrier', J. of KIEEME(in Korean), Vol. 17, No.2, p. 196, 2004
  10. D. H. Chung, S. W. Hur, S. K. Kim, J. U. Lee, C. H. Kim, J. W. Hong, and T. W. Kim, ''Temperature-dependent electrical properties of organic light-emitting diodes depending on cathodes', Current Applied Physics, Vol. 4, Iss. 6, p. 667, 2004
  11. D. H. Chung, S. W. Hur, S. K. Kim, J. U. Lee, M. J. Song, K. U. Jang, S. K. Kim, H. N. Cho, and T. W. Kim, 'Frequency-dependent response in ITO/$Alq_3$ 120/Al organic light-emitting diodes', Current Applied Physics, Vol. 4, p. 543, 2004
  12. S. K. Kim, D. H. Chung, J. W. Hong, T. G. Chung, T. W. Kim, W. J. Lee, and K. U. Jang, 'Effects of buffer layer in organic light-emitting diodes', Mol. Cryst. Liq. Cryst., Vol. 377, p. 129, 2002
  13. S. K. Kim, D. H. Chung, J. W. Hong, T. G. Chung, H. S. Lee, J. W. Park, T. W. Kim, M. J. Song, and W. S. Choi, 'Current-voltage characteristics of organic light-emitting' diodes depending on the application of forward-reverse bias voltage', Mol. Cryst. Liq. Cryst., Vol. 377, p. 133, 2002
  14. S. K. Kim, D. H. Chung, H. S. Lee, H. N. Cho, J. W. Park, J. W. Hong, and T. W. Kim, 'Temperature dependent electrical properties in ITO/TPD/ $Alq_3$/ Al organic light-emitting diodes', Synthetic Metals, Vol. 137, p. 1041, 2003
  15. S. Tokito, H. Tanaka, K. Noda, A. Okada, and Y. Taga, 'Thermal stability in oligomeric triphenylamine /tris(8-quinolinolato) aluminum electroluminescent', IEEE Trans. Electron Devices, 44, p. 1239, 1997 https://doi.org/10.1109/16.605461
  16. Y. Qiu, Y. Gao, Liduo, and D. Zhang, 'Efficient emitting diodes with Teflon buffer layer', Synthetic Metals, Vol. 130, p. 235, 2002
  17. A. Tsuchida, A. Nagata, M. Yamamoto, H. Fukui, M. Sawamoto, and T. Higashimura, 'Hole resonance among more than two carbazole chromophores in poly(N-vinylcarbazole)', macromolecules, 28, p. 1285, 1995

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