Bulletin of the Korean Chemical Society

  • 제26권1호
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  • Pages.115-118
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  • 2005
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Determination of Water Content in Ethanol by Miniaturized Near-Infrared (NIR) System

  • Cho, Soo-Hwa (Department of Chemistry, College of Natural Sciences, Hanyang University) ;
  • Chung, Hoe-Il (Department of Chemistry, College of Natural Sciences, Hanyang University) ;
  • Woo, Young-Ah (College of Pharmacy, Dongduk Women's University) ;
  • Kim, Hyo-Jin (College of Pharmacy, Dongduk Women's University)
  • 발행 : 2005.01.20
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초록

The miniaturized NIR (Near-infrared) spectrometer has been utilized for the determination of water content (1-19% range) in ethanol that is the most popular organic solvent in pharmaceutical industries. It has many potential capabilities that can replace the conventional analyzers especially for the on-line measurement since it is compact, versatile and cost-effective. By using two dimensional (2D) correlation spectroscopy, it was preliminarily investigated to find any unforeseen spectral distortion among the spectra collected from the miniaturized spectrometer. The 2D study revealed that the spectral variation clearly followed the variation of water concentration without any spectral distortion or abnormality. PLS (Partial Least Squares) was employed to build the calibration model and the resulting prediction performance was acceptable and stable over several days. Even though the miniaturized NIR system was evaluated to fairly simple chemical matrix, the overall study demonstrates the sufficient feasibility for diverse practical and industrial applications.

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참고문헌

  1. Burns, D. A.; Ciurczak, E. W. Handbook of Near-Infrared Analysis; Marcel Dekker Inc., New York, 1992
  2. Wetzel, D. L. Anal. Chem. 1983, 55, 1165A https://doi.org/10.1021/ac00262a001
  3. Kamat, M. S.; Lodder, R. A.; DeLuca, P. P. Pharm. Res. 1989, 6, 961 https://doi.org/10.1023/A:1015997530367
  4. Broad, N. W.; Jee, R. D.; Moffat, A. C.; Eaves, M. J.; Mann, W. C.; Dziki, W. Analyst 2000, 125, 2054 https://doi.org/10.1039/b006789j
  5. Woo, Y. A.; Kim, H. J. Useful and Advanced Information in the field of Near Infrared Spectroscopy; Research Signpost: Kerela, India, 2003; chap. 14
  6. Mark, H. Anal. Chem. 1986, 58, 2814 https://doi.org/10.1021/ac00126a051
  7. Lee, S. H.; Nam, J. J.; Son, B. M. Bulll. Korean Chem. Soc. 2003, 24(2), 246 https://doi.org/10.5012/bkcs.2003.24.2.246
  8. Haaland, D. M.; Thomas, E. V. Anal. Chem. 1988, 60, 1202 https://doi.org/10.1021/ac00162a021
  9. Martens, H.; Naes, T. M. Multivariate Calibration; John Wiley and Sons: New York, 1989
  10. Beebe, K. R.; Pell, R. J.; Seasholtz, M. B. Chemometrics: A Practical Guide; John Wiley and Sons: New York, 1998
  11. Noda, I. Appl. Spectrosc. 1993, 47, 1329 https://doi.org/10.1366/0003702934067694
  12. Noda, I.; Dowrey, A. E.; Marcott, C.; Story, G. M.; Ozaki, Y. Appl. Spectrosc. 2000, 54, 236A https://doi.org/10.1366/0003702001950454
  13. Noda, I. Appl. Spectrosc. 2000, 54, 994 https://doi.org/10.1366/0003702001950472
  14. Thomas, E. V.; Haaland, D. M. Anal. Chem. 1990, 62, 1091 https://doi.org/10.1021/ac00209a024
  15. Adachi, D.; Katsumoto, Y.; Sato, H.; Ozaki, Y. Appl. Spectrosc. 2002, 56, 357 https://doi.org/10.1366/0003702021954728
  16. Chung, H.; Lee, J. S.; Ku, M. S. Appl. Spectrosc. 1998, 52, 885 https://doi.org/10.1366/0003702981944436

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  1. A Highly Efficient Turn-On Fluorescent Sensor for Determination of Water in Organic Solvents vol.22, pp.5, 2012, https://doi.org/10.1007/s10895-012-1061-1
  2. In-plane spectroscopy of microfluidic systems made in photosensitive glass vol.19, pp.2, 2013, https://doi.org/10.1007/s00542-012-1626-6
  3. Non-destructive and Rapid Prediction of Moisture Content in Red Pepper (Capsicum annuum L.) Powder Using Near-infrared Spectroscopy and a Partial Least Squares Regression Model vol.39, pp.3, 2014, https://doi.org/10.5307/JBE.2014.39.3.184
  4. Portable platform for rapid and indirect photometric determination of water in ethanol fuel samples vol.6, pp.23, 2014, https://doi.org/10.1039/C4AY02255F
  5. On-Line Application of Near-Infrared Spectroscopy for Monitoring Water Levels in Parts per Million in a Manufacturing-Scale Distillation Process vol.68, pp.4, 2014, https://doi.org/10.1366/13-07260
  6. A new fluorescence method to analyze water traces in gasoline based on the breakup of diphenylquinoxaline-6-amine–Zn–bis-(2,4,6-trichlorophenyl) oxalate vol.13, pp.2, 2015, https://doi.org/10.1007/s10311-015-0502-x
  7. A Prototype Stationary Fourier Transform Spectrometer for Near-Infrared Absorption Spectroscopy vol.69, pp.9, 2015, https://doi.org/10.1366/14-07851
  8. Volume contraction of monohydric alcohols interrogated by planar Bragg grating sensor vol.53, pp.2, 2014, https://doi.org/10.1117/1.OE.53.2.024104
  9. Pb4Br113− cluster as a fluorescent indicator for micro water content in aprotic organic solvents vol.134, pp.3, 2009, https://doi.org/10.1039/b817787b
  10. Determination of Water Content in Aprotic Organic Solvents Using 8-Hydroxyquinoline Based Fluorescent Probe vol.27, pp.12, 2005, https://doi.org/10.5012/bkcs.2006.27.12.2058
  11. Simple and Rapid Quantitative Determination of Di(2-ethylhexyl)phosphoric Acid Concentration Using Near Infrared Spectroscopy vol.27, pp.12, 2005, https://doi.org/10.5012/bkcs.2006.27.12.2101
  12. Progress in two-dimensional (2D) correlation spectroscopy vol.799, pp.1, 2006, https://doi.org/10.1016/j.molstruc.2006.03.053
  13. Combination of a photoacoustic detector with a diffusion sampler for the measurement of water vapor concentration in ethylene glycols for the natural gas industry vol.119, pp.2, 2006, https://doi.org/10.1016/j.snb.2006.01.011
  14. Integrated IR laser system for micro-fluidic detection and analysis vol.135, pp.suppl1, 2005, https://doi.org/10.1016/j.cej.2007.07.041
  15. Influence of dielectric properties on van der Waals/Casimir forces in solid-liquid systems vol.79, pp.19, 2005, https://doi.org/10.1103/physrevb.79.195428
  16. Real-time optical fibre sensor for hydro-alcoholic solutions vol.21, pp.9, 2010, https://doi.org/10.1088/0957-0233/21/9/094035
  17. N-Heteroaryl-1,8-naphthalimide fluorescent sensor for water: Molecular design, synthesis and properties vol.88, pp.3, 2011, https://doi.org/10.1016/j.dyepig.2010.07.009
  18. Optimised determinations of water in ethanol by encoded photometric near-infrared spectroscopy: A special case of sequential standard addition calibration vol.690, pp.1, 2005, https://doi.org/10.1016/j.aca.2011.02.002
  19. In-plane spectroscopy with optical fibers and liquid-filled APEX™ glass microcuvettes vol.23, pp.10, 2005, https://doi.org/10.1088/0960-1317/23/10/107001
  20. Optimization of in-line near-infrared measurement for practical real time monitoring of coating weight gain using design of experiments vol.47, pp.1, 2005, https://doi.org/10.1080/03639045.2020.1862166