Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Significant Improvement of Catalytic Efficiencies in Ionic Liquids

  • Song, Choong-Eui (Institute of Basic Science, Department of Chemistry, Sungkyunkwan University) ;
  • Yoon, Mi-Young (Institute of Basic Science, Department of Chemistry, Sungkyunkwan University) ;
  • Choi, Doo-Seong (Institute of Basic Science, Department of Chemistry, Sungkyunkwan University)
  • Published : 2005.09.20
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Abstract

The use of ionic liquids as reaction media can confer many advantages upon catalytic reactions over reactions in organic solvents. In ionic liquids, catalysts having polar or ionic character can easily be immobilized without additional structural modification and thus the ionic solutions containing the catalyst can easily be separated from the reagents and reaction products, and then, be reused. More interestingly, switching from an organic solvent to an ionic liquid often results in a significant improvement in catalytic performance (e.g., rate acceleration, (enantio)selectivity improvement and an increase in catalyst stability). In this review, some recent interesting results which can nicely demonstrate these positive “ionic liquid effect” on catalysis are discussed.

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