Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Excitation Energy Transfer Rate Constants in meso-meso Linked Zn(II) Porphyrin Arrays with Energy Accepting 5,15-Bisphenylethynylated Zn(II) Porphyrin

  • Ko, Da-Mee (Center for Ultrafast Optical Characteristics Control, Yonsei University) ;
  • Kim, Hee-Young (Department of Chemistry, Yonsei University) ;
  • Park, Jin-Hee (Center for Ultrafast Optical Characteristics Control, Yonsei University) ;
  • Kim, Dong-Ho (Center for Ultrafast Optical Characteristics Control, Yonsei University) ;
  • Sim, Eun-Ji (Department of Chemistry, Yonsei University)
  • Published : 2005.10.20
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Abstract

The excitation energy transfer process occurring in energy donor-acceptor linked porphyrin array system is theoretically simulated using the on-the-fly filtered propagator path integral method. The compound consists of an energy donating meso-meso linked Zn(II) porphyrin array and an energy accepting 5,15-bisphenylethynylated Zn(II) porphyrin, in which the donor array and the acceptor are linked via a 1,4-phenylene spacer. Real-time path integral simulations provide time-evolution of the site population and the excitation energy transfer rate constants are determined. Simulations and experiments show an excellent agreement indicating that the path integration is a useful tool to investigate the energy transfer dynamics in molecular assemblies.

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References

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