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Physical Properties of High-Solid Coatings with Acrylic Resins Containing Caprolactone Group and HDI-Trimer

Caprolactone기 함유 아크릴수지와 HDI-Trimer에 의한 하이솔리드 도료의 도막물성

  • Jo, Hye-Jin (Department of Chemical Engineering, Myongji University) ;
  • Shim, Il-Woo (Department of Chemical Engineering, Myongji University) ;
  • You, Hyuk-Jae (Department of Chemical Engineering, Myongji University) ;
  • Wu, Jong-Pyo (Department of Chemical Engineering, Myongji University) ;
  • Kim, Myung-Soo (Department of Chemical Engineering, Myongji University) ;
  • Hahm, Hyun-Sik (Department of Chemical Engineering, Myongji University) ;
  • Park, Hong-Soo (Department of Chemical Engineering, Myongji University) ;
  • Baik, Woon-Phil (Department of Chemistry, Myongji University)
  • 조혜진 (명지대학교 공과대학 화학공학과) ;
  • 심일우 (명지대학교 공과대학 화학공학과) ;
  • 유혁재 (명지대학교 공과대학 화학공학과) ;
  • 우종표 (명지대학교 공과대학 화학공학과) ;
  • 김명수 (명지대학교 공과대학 화학공학과) ;
  • 함현식 (명지대학교 공과대학 화학공학과) ;
  • 박홍수 (명지대학교 공과대학 화학공학과) ;
  • 백운필 (명지대학교 이과대학 화학과)
  • Published : 2004.12.31

Abstract

High-solid coatings were prepared by blending of previosly synthesized acrylic resins and hexamethylene diisocyanate-trimer and curing it at room temperature. The characterization of the films of the prepared coatings was performed. The impact resistance, cross-hatch adhesion, $60^{\circ}$specular gloss, and heat resistance of the films proved to be good, and the pencil hardness and drying time proved to be slightly poor. Especially, there was a remarkable improvement in the heat resistance. This improvement may stem from the regular arrangement of ethyl groups introduced into the acrylic resin. As a result of Rigid-body pendulum visco-elasticity measurement, dynamic $T_g$ values of cured films increased with dynamic $T_g$ values.

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References

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