Journal of the Korean institute of surface engineering (한국표면공학회지)

The Korean Institute of Surface Engineering (한국표면공학회)
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Electric Conductivities of LaC $l_3$-LiCl Binary Melts

용융 LaC $l_3$-LiCl 2성분계 혼합염의 전도도

  • 김기호 (충북대학교 재료공학과)
  • Published : 2004.10.01
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Abstract

Electric Conductivities of $LaCl_3$-LiCl binary melts have been measured by the Kohlausch bridge method over the range of their liquidus temperatures to about 1200 K. The electric conductivity increases with the content of LiCl for all over the composition range of binary melts. Composition dependence of the electric conductivity and molar conductivity for the binary melt shows a non-linear relation from the additivity line, and the deviations displays a maximum value at about 60 mol % LiCl. This suggest the existence of the complex ion of$ LaCl_{4}^{-}$ in the melt. Activation energy for electric conductivity of the binary melts decrease monotonously with increasing content of LiCl.l.

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References

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