DOI QR코드

DOI QR Code

Generation of Microcellular Foams in Viscoelastic Polymer Solutions

점탄성 폴리머 용액에서의 초미세 폼의 생성

  • 강성린 (중앙대학교 대학원 기계공학부) ;
  • 김기영 (중앙대학교 대학원 기계공학) ;
  • 곽호영 (중앙대학교 기계공학부)
  • Published : 2004.06.01

Abstract

The growth of the critical size bubble by diffusion process in viscoelastic medium was treated by an integral method for the concentration boundary layer adjacent to the bubble wall. In this study, we obtained a set of the first order time dependent equations to obtain bubble radius and gas pressure inside the bubble simultaneously. The calculated final cell sizes depending on the initial saturation pressure are in close agreement with the observed ones. The governing equations developed in this study may be used in polymer processing of microcellular foams.

Keywords

References

  1. Gent, A. N. and Tompkins, D. A., 1969, 'Nucleation and Growth of Gas Bubbles in Elastomers,' Journal of Applied Physics, Vol. 40, pp. 2520-2525 https://doi.org/10.1063/1.1658026
  2. Stewart, C. W., 1970, 'Nucleation and Growth of Bubbles in Elastomers,' Journal of Polymer Science: A-2, Vol. 8, pp. 937-955 https://doi.org/10.1002/pol.1970.160080609
  3. Han, J. H. and Han, C. D., 1990, 'Bubble Nucleation in Polymeric Liquids. I. Bubble Nucleation in Concentrated Polymer Solutions,' Journal of Polymer Science: Part B., Vol. 28, pp. 711-741 https://doi.org/10.1002/polb.1990.090280509
  4. Han, C. D. and Yoo, H. J., 1981, 'Studies on Structural Foam Processing. IV. Bubble Growth During Mold Filling,' Polymer Engineering & Science, Vol. 21, pp. 518-533 https://doi.org/10.1002/pen.760210903
  5. Colton, J. S. and Suh, N. P., 1987, 'The Nucleatio of Microcellular Thermoplastic Foam With Additives: Part II: Experimental Results and Discussion,' Polymer Engineering and Science, Vol. 21, pp. 518-533 https://doi.org/10.1002/pen.760270703
  6. Goel, S. K. and Beckman, E. J., 1994, 'Generation of Microcellular Polymeric Foams Using Supercritical Carbon Dioxide. I: Effect of Pressure and Temperature on Nucleation,' Polymer Engineering and Science, Vol. 34, pp. 1137-1147 https://doi.org/10.1002/pen.760341407
  7. Kim, K. Y., Kang, S. L. and Kwak, H., 2004, 'Bubble Nucleation and Growth in Polymer Solutions,' will be published in Polymer Engineering & Science
  8. Rosner, D. E. and Epstein, P. S., 1972, 'Effects of Interface Kinetics, Capillarity and Solute Diffusion on Bubble Growth Rates in Highly Supersaturated Liquids,' Chemical Engineering Science, Vol. 27, pp. 69-88 https://doi.org/10.1016/0009-2509(72)80142-8
  9. Arefmanesh, A. and Advani, S. G., 1991, 'Diffusion Induced Growth of a Gas Bubble in a Viscoelastic Fluid,' Rheologica Acta, Vol. 30, pp. 274-283 https://doi.org/10.1007/BF00366641
  10. Arefmanesh, A., Advani, S. G. and Michaehides, E. E., 1992, 'An Accurate Numerical Solution for Mass Diffusion-Induced Bubble Growth in Viscous Liquids Containing Limited Dissolved Gas,' International Journal of Heat and Mass Transfer, Vol. 35, pp. 1711-1722 https://doi.org/10.1016/0017-9310(92)90141-E
  11. Blander, M. and Katz, J. L., 1975, 'Bubble Nucleation in Liquids,' AIChE Journal, Vol. 21, pp. 833-848 https://doi.org/10.1002/aic.690210502
  12. Kwak, H. and Kim, Y. W., 1998, 'Homogeneous Nucleation and Macroscopic Growth of Gas Bubble in Organic Solutions,' International Journal of Heat and Mass Transfer, Vol. 41, pp. 757-767 https://doi.org/10.1016/S0017-9310(97)00182-8
  13. Incropera, F. P. and Dewitt, D. P., 1981, Fundamentals of Heat and Mass Transfer, 2nd Ed., John Wiley and Sons
  14. Bird, R. B., Stewart, W. E. and Lightfoot, E. N., 1960, Transport phenomena, Wiley, New York
  15. Kang, S. L., Kim, K. Y. and Kwak, H., 2004, 'Bubble Nucleation in Polymer Solutions,' Polymer(Korea), Vol. 28, pp. 51-58
  16. Kwak, H. and Panton, R. L., 1983, 'Gas Bubble Formation in Non-Equilibrium Water-Gas Solutions,' Journal of Chemical Physics, Vol. 78, pp. 5795-5799 https://doi.org/10.1063/1.445422
  17. Goel, S. K. and Beckman, E. J., 1995, 'Nucleation and Growth in Microcellular Materials: Supercritical $CO_2$ as Foaning Agent' https://doi.org/10.1002/aic.690410217