Effect of Impressed Potential on the SCC of Al-Brass

Al-황동의 응력부식균열 특성에 미치는 인가전위의 영향

  • Published : 2004.02.01

Abstract

In general, the protection method of Shell and Tube Type heat exchanger for a vessel has been applied as a sacrificial anode, which is attached at the inner side of the shell. However, this is an insufficient protection method for tube. Therefore, a more suitable method, such as the impressed current cathodic protection for tube protection, is required. Al-brass is the raw material of tubes for heat exchanger of a vessel where seawater is used for cooling the water. It has a high level of heat conductivity, excellent mechanical properties, and a high level of corrosion resistance, due to a cuprous oxide (Cu$_2$O) layer against th seawater. However, in actuality, it has been reported that Al-brass tubes for heat exchanger of a vessel can produce local corrosion, such as stress corrosion cracking (SCC). This paper studied the effect of impressed potential on the stress corrosion cracking of Al-brass for impressed current cathodic protection in 3.5% NaCl +0.1% NH$_4$OH solution, under flow by a constant displacement tester. Based on the test results, the latent time of SCC, stress corrosion crack propagation, and the dezincification phase of Al-brass are investigated.

Keywords

References

  1. 한국해양공학회지 v.17 no.1 STS316L용접재의 표면파에 의한 잔류응력 측정과 균열진전시의 음향방출특성 남기우;박소순;안석환
  2. Standard Practice for Microetching Metal and Alloys ASTM Standards-E407
  3. Corrosion Atlas Evert,D.D.
  4. Int. J. of Fracture Mech. v.6 no.4 The Initiation of Fatigue Cracks from Notches in Mild Steel Plates Jack,A.R.;Price,A.T.
  5. Kor. Ins. of Gas. v.7 no.2 The Effect of Stress on SCC of Heat Exchanger Tube for LNG Vessel Jeong,H.K.;Lim,U.J.
  6. Principles and Prevention of Corrosion Jones,D.A.
  7. Metal Handbook v.13 Corrosion(9th ed.) Jones,R.H.;Ricker,R.E.
  8. Principles and Prevention of Corrosion Jones,D.A.
  9. Corrosion and Corrosion Control(3rd ed.) Revie,R.W.;Uhling,H.H.
  10. Stress Corrosion Cracking and Hydrogen Embrittlement of Iron Base Alloys Staehle,R.W.