Korean Journal of Environmental Agriculture (한국환경농학회지)

The Korean Society of Environmental Agriculture (한국환경농학회)
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An Improved Method for Multiresidue Analysis of Pesticides in Lettuce, Chinese Cabbage and Green Pepper by Gas Chromatography

  • Hong, Yong-Soon (School of Agricultural Biotechnology, Seoul National University) ;
  • Park, Hee-Won (School of Agricultural Biotechnology, Seoul National University) ;
  • Choi, Hoon (School of Agricultural Biotechnology, Seoul National University) ;
  • Moon, Joon-Kwan (School of Agricultural Biotechnology, Seoul National University) ;
  • Kim, Min-Jeong (Department of Agricultural Chemistry, Kyungpook National University) ;
  • Kim, Jang-Eok (Department of Agricultural Chemistry, Kyungpook National University) ;
  • Lee, Young-Deuk (Division of Life and Environmental Science, Daegu University) ;
  • Oh, Chang-Hwan (Department of Agricultural Chemistry, Kyungpook National University) ;
  • Kim, Jeong-Han (School of Agricultural Biotechnology, Seoul National University)
  • Published : 2004.09.30
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Abstract

For the improvement of gas chromatographic analysis of multiple pesticide residues in green pepper, lettuce and Chinese cabbage, multiresidue test mixtures (MRTMs) of 10 groups (ECD 5 groups and NPD 5 groups) and a recovery test mixture (RTM) of 18 compounds (11 compounds for ECD and 7 compounds for NPD) were established based on retention time and response to relevant detectors. A new extraction solvent (acetone: acetonitrile=1 : 9) and a clean up eluent (hexane: dichloromethane : acetonitile = 50 : 48.5 : 1.5) for solid-phase extraction (SPE) cartridge were selected to test two types of multiresidue methods (MRM I and MRM II). MRM II provided high recovery better than MRM I when RTM was tested Recovery experiment with MRTMs which was conducted using MRM II resulted in that more than seventy percents of compounds were recovered in the range of $50{\sim}140%$, while 9% of compounds were over 140% of recovery and only $7{\sim}8$ compounds failed to detect. MRM II, an improved method, could be employed for screening residues of 190 pesticides in those vegetables.

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References

  1. Stajnbaher, D. and Zupandc-Kralj, L. (2003) Multiresidue method for determination of 90 pesticides in fresh fruits and vegetables using solid-phase extraction andgas chromatography-mass spectrornetry, Journal of Chromatography A 185-198
  2. Chun, O. K. and Kang, H. G. (2003) Estimation of risk of pesticide exposure, by food intake, to Koreans, Food and Chemical Toxicology 41, 1063-1076 https://doi.org/10.1016/S0278-6915(03)00044-9
  3. Sicbaldi, E, Sarra, A., Mutti, D. and Bo, P. F. (1997)Use of gas-liquid chromatography with electron-capture and thermionic-sensitive detection for the quantitation and identification of pesticide residues, J. Chrormtography A 765, 13-22 https://doi.org/10.1016/S0021-9673(96)00975-2
  4. Fillion, J., Sauve, F. and Selwyn, J. (2000) Multiresidue method for the determination of residues of 251 pesticides in fruits and vegetables by gas chromatography/mass spectrometry and liquid chromatography with fluorescence detection, Journal of AOAC International 83, 698-713
  5. Moye, H. A. (1999) Emerging methods, Extractions and Cleanup, In Pesticide Residues in Foods Methods, Techniques, and Regulations, JOHN WILEY & SONS, New York, USA, p.139-209
  6. FDA. (1994) Multriesidue methods section 302-304: Pesticides Analytical Manual, Vol 1, 3th Edition, Washington, DC, U.S
  7. Clive, T. (2004) The Pesticide Manual 13th Edition,BCPC, Hampshire, UK
  8. KFDA (2002) Food Code method, 83, 258-261
  9. Lehotay, S. J. (1997) Supercritical fluid extraction of pesticides in foods, J. Chromatogr. A 785, 289-312 https://doi.org/10.1016/S0021-9673(97)00461-5
  10. Seiber, J. N. (1999) The Analytical Approach, In Pesticide Residues in Foods Methods, Techniques, and Regulations, JOHN WILEY & SONS, New York, USA, p.1-16,P.17-61
  11. Milton, A., Luke, M. A., and Masumoto, H. T. (1986)Pesticides Residue Analysis of Foods, In Pesticides and plant Growth regulators, Academic Press, Orlando, USA,P.161-200
  12. Motohashi, M, Nagashima, H., Parkanyi, C. and Subrahmanyan, B. (1996) Official multiresidue method of pesdcides analysis in vegetables, fruits and soil, J. Chromatogr. A 754, 333-346 https://doi.org/10.1016/S0021-9673(96)00576-6
  13. Ahmed, F. E. (2001) Analyses of pesticides and their metabolites in foods and drinks, trends in Analytial Chemistry 20(11), 649-661 https://doi.org/10.1016/S0165-9936(01)00121-2
  14. Schenck, F. J., Calderon, L. and Saudarg, D. E. (1996) Florisil solid-phase extraction cartridges for cleanup of organochlorine pesticides in foods, Journal of AOAC International 79, 1454-1458
  15. Sabik, H., Jeannot, R and Roudeau, B. (2000) Multiresidue methods using solid-phase extraction techniques for monitoring priority pesticides, including triazines and degradation products, in ground and surface waters, J. Chromatogr. A 885, 217-236 https://doi.org/10.1016/S0021-9673(99)01084-5
  16. Choi, K. I., Bea, H. R, Jeong, S. S. and Sung, K. Y.(2002) Multiresidue analysis of pesticides using gas chromatography with electron capture and nitrogen phosphorus detector, The Koreaon Society of Analytical Sciences, 126

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